Pt2(NH3)2Cl2(μ-pivalamidato)2(CH2COCH3) | 870251-68-6

• 英文名称: Pt2(NH3)2Cl2(μ-pivalamidato)2(CH2COCH3)
• CAS: 870251-68-6
• 化学式: C₁₃H₃₁Cl₂N₄O₃Pt₂
• 分子量: 752.48
• InChiKey: XGXBEIKAKRHRPZ-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  potassium tetranitroplatinate(IV) 、 Pt2(NH3)2Cl2(μ-pivalamidato)2(CH2COCH3) 以 水 、 丙酮 为溶剂， 以13%的产率得到[Pt2(NH3)2Cl2(μ-pivalamidato)2(CH2COCH3)]2(Pt(NO2)4)
  参考文献：
  名称：

  Mixed‐Valent Linear Chain Pt ₂ PdPt ₂ Complexes

  摘要：

  AbstractPentanuclear linear‐chain PtPd complexes {[Pt2(NH3)2X2(μ‐pivalamidato)2(CH2COCH3)]2[PdX′4]}·2CH3COCH3 (X = X′ = Cl (1a), X = Cl, X′ = Br (1b), X = Br, X′ = Cl (1c), X = X′ = Br (1d)) composed of a monomeric PdII complex sandwiched by two amidato‐bridged dimeric PtIII units were synthesized from the reaction between the acetonyl dinuclear PtIII complexes having equatorial halide ligands [Pt2(NH3)2X2(μ‐pivalamidato)2(CH2COCH3)]X″ (X = Cl (2a), Br (2b), X″ = NO3–, CH3C6H4SO3–) and K2[PdX′4] (X′ = Cl, Br). The X‐ray crystallographic analysis of 1a–1d shows that the complexes have metal–metal bonded linear Pt2PdPt2 structures. The pentanuclear PtPd complexes have either an arch backbone structure or a sigmoid backbone structure, depending on the solvent of crystallization. The UV/Vis/NIR spectra clearly show the existence of a rare charge‐transfer band from Pd to Pt in the pentanuclear PtPd complexes. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)

  DOI：

  10.1002/ejic.200601247

文献信息

• Synthesis of the Pivalamidate-Bridged Pentanuclear Platinum(II,III) Linear Complexes with Pt···Pt Interactions
  作者：Kazuko Matsumoto、Saiko Arai、Masahiko Ochiai、Wanzhi Chen、Ayako Nakata、Hiromi Nakai、Shuhei Kinoshita

  DOI：10.1021/ic050942a

  日期：2005.11.1

  Pentanuclear linear chain Pt(II,III) complexes [[Pt2(NH3)2X2((CH3)3CCONH)2(CH2COCH3)]2[PtX'4]].nCH3COCH3 (X = X' = Cl, n = 2 (1a), X = Cl, X' = Br, n = 1 (1b), X = Br, X' = Cl, n = 2 (1c), X = X' = Br, n = 1 (1d)) composed of a monomeric Pt(II) complex sandwiched by two amidate-bridged Pt dimers were synthesized from the reaction of the acetonyl dinuclear Pt(III) complexes having equatorial halide

  五核线性链Pt（II，III）络合物[[Pt2（NH3）2X2（（CH3）3CCONH）2（CH2CO ）] 2 [PtX'4]]。n CO （X = X'= Cl，n = 2（1a ），X = Cl，X'= Br，n = 1（1b），X = Br，X'= Cl，n = 2（1c），X = X'= Br，n = 1（1d））由由具有赤道卤化物配体[Pt2（NH3）2X2（（ ）3CCONH）2（CH2CO ）的乙酰基双核Pt（III）配合物的反应合成了一个单体Pt（II）配合物，该配合物被两个酰胺基桥接的Pt二聚体夹在中间X''（X = Cl（2a），Br（2b），X''= NO3-， C6H4SO3-，BF4-，PF6-，ClO4-），其中K2 [PtX'4]（X'= Cl，Br ）。1a-1d的X射线结构表明该配合物具有金属-金属键合的线性Pt5结构，金属的氧化态约为Pt（III）-Pt（III）