| 1356841-00-3

• CAS: 1356841-00-3
• 化学式: C₄₂H₃₃IrN₇O*F₆P
• 分子量: 988.954
• InChiKey: HNGZYNORMDAFCW-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  2-氨甲基吡啶 、 bis(2-phenyl-pyridine)(5-chloromethylcarbonylamino-1,10-phenanthroline)iridium(III) hexafluorophosphate 在 KI 、 triethylamine 作用下， 以 四氢呋喃 为溶剂， 以82%的产率得到
  参考文献：
  名称：

  A phosphorescent chemosensor for Cu2+ based on cationic iridium(III) complexes

  摘要：

  A cationic phosphorescent iridium complex 1 was synthesized, which can selectively detect Cu2+ confirmed by the luminescence spectra titration. In the presence of Cu2+, the obvious decrease of the luminescence intensity at 600 nm was investigated. The complex has been shown to display high selectivity for Cu2+ over other metal ions. The strong selective coordination interaction with Cu2+ is responsible for the significant change of the luminescence spectra, which is further confirmed by ESI-MS. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2011.11.006