Ta(CH2CH2CH2CH2)(η(5)-C5Me5)(η(4)-buta-1,3-diene) | 71860-93-0

• 英文名称: Ta(CH2CH2CH2CH2)(η(5)-C5Me5)(η(4)-buta-1,3-diene)
• CAS: 71860-93-0
• 化学式: C₁₈H₂₉Ta
• 分子量: 426.376
• InChiKey: WVOCCQHERFYSBG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  、 乙烯 以 not given 为溶剂， 生成 Ta(CH2CH2CH2CH2)(η(5)-C5Me5)(η(4)-buta-1,3-diene)
  参考文献：
  名称：

  Synthesis and reactivity of new polyhydride compounds of tantalum(V)

  摘要：

  DOI：

  10.1021/ja00372a011

文献信息

• Synthesis, characterization and reactions of ethylene complexes bearing Ta(η5-C5R5)(η4-buta-1,3-diene) fragments (R = H, Me)
  作者：Kazushi Mashima、Yoshiyuki Tanaka、Akira Nakamura

  DOI：10.1016/0022-328x(95)05638-6

  日期：1995.10

  The ethylene complex TaCp(eta(4)-butadiene)(eta(2)-C2H4)(PMe(3)) (2) was prepared in 77% yield by the reaction of TaCl(2)Cp(eta(4)-butadiene) (la) with 2 equiv. of EtMgI in the presence of 1 equiv. of PMe(3). In the absence of PMe(3), TaCp(eta(4)-butadiene)(eta(2)-C2H4) (3) was initially formed but this gradually decomposed to give the known metallacyclic compound Ta(CH2CH2CH2CH2)Cp(eta(4)-butadiene) (4). Carbonylation of 2 afforded a monocarbonyl complex TaCp(butadiene)(CO)(PMe(3)) (6) and a dicarbonyl complex TaCp(butadiene)(CO)(2) (7), while reaction of 2 with diphenylacetylene under UV irradiation gave a reversible addition product TaCp(eta(4)-butadiene)(eta(2)-PhC=CPh)(PMe(3)) (8).