[Zn2(N,N,N′,N′-tetrakis(2-quinolylmethyl)-2-hydroxy-1,3-propanediamine)(P1P2-diphenylpyrophosphate)(water)](perchlorate) | 1453273-82-9

• 英文名称: [Zn2(N,N,N′,N′-tetrakis(2-quinolylmethyl)-2-hydroxy-1,3-propanediamine)(P1P2-diphenylpyrophosphate)(water)](perchlorate)
• 英文别名: [Zn₂(N,N,N′,N′-tetrakis(2-quinolylmethyl)-2-hydroxy-1,3-propanediamine)(P¹P²-diphenylpyrophosphate)(water)](perchlorate)
• CAS: 1453273-82-9
• 化学式: C₅₅H₄₉N₆O₉P₂Zn₂*ClO₄
• 分子量: 1230.21
• InChiKey: MDLFKGBFHIOBNI-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  zinc perchlorate 、 disodium P¹P²-diphenylpyrophosphate 、 N,N,N’,N’-tetrakis(2-quinolylmethyl)-2-hydroxy-1,3-propanediamine 以 四氢呋喃 、 水 为溶剂， 以66%的产率得到[Zn2(N,N,N′,N′-tetrakis(2-quinolylmethyl)-2-hydroxy-1,3-propanediamine)(P1P2-diphenylpyrophosphate)(water)](perchlorate)
  参考文献：
  名称：

  Quantitative Fluorescent Detection of Pyrophosphate with Quinoline-Ligated Dinuclear Zinc Complexes

  摘要：

  Dinuclear zinc complex [Zn-2(TQHPN)-(AcO)](2+) exhibits characteristic fluorescence response (lambda(ex) = 317 nm and lambda(em) = 455 nm) toward pyrophosphate (PPi) with maximum fluorescence upon 1:1 Zn-2(TQHPN)-PPi complex formation. The crystallographic investigation utilizing (PP2)-P-1-Ph(2)PPi revealed that the fluorescent response mechanism is due to intramolecular excimer formation of two quinoline rings.

  DOI：

  10.1021/ic401605m