1-[(η5-cyclopentadienyl)(triphenylphosphine)carbonyliron]-1,12-dicarba-closo-dodecaborane | 666840-95-5

• 英文名称: 1-[(η5-cyclopentadienyl)(triphenylphosphine)carbonyliron]-1,12-dicarba-closo-dodecaborane
• CAS: 666840-95-5
• 化学式: C₂₆H₃₁B₁₀FeOP
• 分子量: 554.462
• InChiKey: AXWGZNUFJAMKRO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1-[(η5-cyclopentadienyl)dicarbonyliron]-1,12-dicarba-closo-dodecaborane 、 三苯基膦 以 苯 为溶剂， 以97%的产率得到1-[(η5-cyclopentadienyl)(triphenylphosphine)carbonyliron]-1,12-dicarba-closo-dodecaborane
  参考文献：
  名称：

  Metal−Metal Communication through Carborane Cages Supporting Electroactive [η⁵-CpFe(CO)₂] Substituents

  摘要：

  A family of eta(5)-CpFe(CO)(2)-substituted closo-carboranes was synthesized and characterized, including cyclic voltammetry measurements. Like the previously reported bimetallic compound 1,12-[eta(5)-CpFe(CO)(2)](2)-1,12-C2B10H10 (8), 1,10-[eta(5)-CpFe(CO)(2)](2)-1,10-C2B8H8 (9) produces two dissimilar and irreversible one-electron oxidations within the same range, suggesting that it also exhibits through-cage electronic communication between iron centers. Structures determined by X-ray diffraction studies are reported for 1-[eta(5)-CpFe(PPh3)(CO)]-1,12-C2B10H11 (5), 1,12-[eta(5)-CpFe(CO)(2)](2)-1,12-C2B10H10 (8), and 1,10-[eta(5)-CpFe(CO)(2)](2)-1,10- C2B8H8(9).

  DOI：

  10.1021/om030514h