[CpFe(CO)(κ-2 Se,S-SeC(S)O-4-C6H4Cl] | 886848-13-1

• 英文名称: [CpFe(CO)(κ-2 Se,S-SeC(S)O-4-C6H4Cl]
• CAS: 886848-13-1
• 化学式: C₁₃H₉ClFeO₂SSe
• 分子量: 399.539
• InChiKey: BUTSSDCCTZHRTR-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  以 四氢呋喃 为溶剂， 以90%的产率得到[CpFe(CO)(κ-2 Se,S-SeC(S)O-4-C6H4Cl]
  参考文献：
  名称：

  Selenothiocarbonate complexes of iron: Structure of CpFe(CO)2SeC(S)O-4-C6H4Cl

  摘要：

  Stable complexes of general formula CpFe(CO)(2)SeC(S)OR, where R = Ph (1a), 4-C6H4Cl (1b), 4-C6H4F (1c), C6F5 (1d), 4-C6H4CH3 (1e), were prepared by the reaction of (mu-Se)[CpFe(CO)(2)](2) with ROC(S)Cl at room temperature. When a THF solution of 1 was photolyzed the chelate complexes CpFe(CO)(kappa(2)Se,S-SeC(S)OR) (2) were obtained in good yields. All of these complexes have been characterized by elemental analyses, IR and H-1 NMR spectroscopy, The structure of CpFe(CO)(2)SeC(S)O-4-C6H4Cl (1b) is reported. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2005.09.024