| 194300-61-3

• CAS: 194300-61-3
• 化学式: C₃₇H₃₅OPRu
• 分子量: 627.728
• InChiKey: KZQZLLUPYOSNET-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  Cp*RuCl(CCHPh)(PPh3) 、 一氧化碳 在 Et₃N 作用下， 以 not given 为溶剂， 以85%的产率得到
  参考文献：
  名称：

  Reaction of the in-Situ-Generated Ruthenium−Acetylide Complex C₅Me₅Ru(PPh₃)C⋮CPh with Small Molecules

  摘要：

  A coordinatively unsaturated acetylide species C5Me5Ru(PPh3)C=CPh (1) was generated in situ from the reaction of ruthenium-vinylidene complex C5Me5Ru(Cl)(PPh3)=C=CHPh (2) with Et3N. The vinylidene complex 2 was prepared from the substitution. reaction of C5Me5Ru(PPh3)(2)Cl with PhC=CH. The in-situ-generated 1 was found to react readily with a variety of small molecules. For example, the reaction of 1 with CO produced the stable adduct C5Me5Ru(CO)(PPh3)C=CPh (3) in 85% yield, the structure of which was established by X-ray crystallography. The similar reactions of 1 with H-2 and PhC=CPh also gave the hydride complex C5Me5Ru(PPh3)(H)(H2C=CHPh) (4) (76% yield) and the alkyne complex C5Me5Ru(PPh3)(PhC=CPh)C=CPh (5) (85% yield), respectively. The reaction of 1 with CO2 produced the carboxylate complex C5Me5Ru(PPh3)(eta(2)-O2CC=CPh) (6) from the insertion of CO2 to the ruthenium-acetylide carbon bond.

  DOI：

  10.1021/om9705012

文献信息

• Bruce, Michael I.; Hall, Ben C.; Zaitseva, Natasha N., Journal of the Chemical Society, Dalton Transactions, 1998, # 11, p. 1793 - 1803
  作者：Bruce, Michael I.、Hall, Ben C.、Zaitseva, Natasha N.、Skelton, Brian W.、White, Allan H.

  DOI：——

  日期：——
• An unusual Cu2Ru2 cluster containing a tetrameric phenylethynyl ligand
  作者：Michael I. Bruce、Natasha N. Zaitseva、Brian W. Skelton、Allan H. White

  DOI：10.1016/j.jorganchem.2007.11.002

  日期：2008.4

  The reaction between RuCl(PPh(3))(2)Cp* and Cu(CCPh)}(n) in refluxing benzene afforded Ru(2)Cu(2)(C(2)Ph)(5)H(2)(Cl)(PPh(3))Cp(2)*, which contains an unusual tetramer of the phenylethynyl group which interacts with an Ru...Cu...Cu...Ru chain. The second Ru atom is part of a ruthenocenyl moiety which interacts weakly with the second Cu atom, and bears a vinylidene which bridges an Ru - Cu vector. The structure of a second modification of Ru(C CPh)(CO)(PPh(3))Cp* is also reported. (C) 2007 Elsevier B. V. All rights reserved.