{Pd(1,2-bis(diphenylphosphanyl)ethane)(C2H4)} | 94929-16-5

• 英文名称: {Pd(1,2-bis(diphenylphosphanyl)ethane)(C2H4)}
• CAS: 94929-16-5
• 化学式: C₂₈H₂₈P₂Pd
• 分子量: 532.898
• InChiKey: QZQQMCCXRVFHCJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  {Pd(1,2-bis(diphenylphosphanyl)ethane)(C2H4)} 、 1,2-双(二环己基磷基)-乙烷 以 四氢呋喃 为溶剂， 生成 {Pd(1,2-bis(diphenylphosphino)ethane)(1,2-bis(dicyclohexylphosphino)ethane)}
  参考文献：
  名称：

  Mixed biphosphine complexes of palladium(0); the structure of “bis(diphenylphosphino)ethane”-“bis(dicyclohexylphosphino)ethane” palladium(0)

  摘要：

  A range of mixed biphosphine complexes of palladium(0) has been prepared and characterized by P-31 NMR spectroscopy. The complexes disproportionate in solution at rates which depend on the nature of the ligands. The structure of [Pd(dcpe)(dppe)] has been established in an X-ray diffraction study.

  DOI：

  10.1016/s0277-5387(00)81751-9
• 作为产物：
  描述：

  1,2-二(二苯基膦基)乙烷二氯化钯(II) 在 ethene 、 LiBHEt₃ 作用下， 以 四氢呋喃 为溶剂， 生成 {Pd(1,2-bis(diphenylphosphanyl)ethane)(C2H4)}
  参考文献：
  名称：

  Mixed biphosphine complexes of palladium(0); the structure of “bis(diphenylphosphino)ethane”-“bis(dicyclohexylphosphino)ethane” palladium(0)

  摘要：

  A range of mixed biphosphine complexes of palladium(0) has been prepared and characterized by P-31 NMR spectroscopy. The complexes disproportionate in solution at rates which depend on the nature of the ligands. The structure of [Pd(dcpe)(dppe)] has been established in an X-ray diffraction study.

  DOI：

  10.1016/s0277-5387(00)81751-9

文献信息

• An η²transition state for the insertion of [Pd(dppe)] fragments into the phosphorus–carbon bonds of phosphiranepentacarbonyltungsten complexes. Crystal and molecular structures of (2R,3S,4R)- and (2R,3S,4S)-[Pd(dppe)(CHPhCHPhPPh)-W(CO)₅], dppe = 1,2-bis(diphenylphosphanyl)ethane
  作者：Duncan Carmichael、Peter B. Hitchcock、John F. Nixon、François Mathey、Louis Ricard

  DOI：10.1039/c39890001389

  日期：——

  Evidence for a transition state involving η2 co-ordination of a P–C bond to [Pd(dppe)] is obtained from an analysis of the insertion of [Pd(dppe)] fragments into (E)- and (Z)-[W(CO)5(PPh–CHPh–CHPh)] complexes.

  证据涉及η过渡状态2在P-C键的统筹[钯（DPPE）]是从插入的分析获得的[将Pd（DPPE）]片段插入（ë） -和（Ž） - [W（CO）5（PPh–CHPh–CHPh）]配合物。
• An η²transition state for the insertion of M(PR₃)₂fragments (M = Pd or Pt) into the phosphorus–carbon bonds of pentacarbonyl(phosphirane)tungsten complexes
  作者：Duncan Carmichael、Peter B. Hitchcock、John F. Nixon、François Mathey、Louis Ricard

  DOI：10.1039/dt9930001811

  日期：——

  4S*)-(±)-, (2S*3R*4R*)-(±)- and (2S*,3S*,4R*)-(±)-[(Ph3P)2Pt(CHPhCHPhPPh)W(CO)5]; and trans-(2S*,3S*,4R*)-(±)-[(Ph3P)(OC)Pt-(CHPhCHPhPPh)W(CO)5]. The crystal and molecular structures of (Z)-[W(CO)5([graphic omitted]HPh)], (2R*,3S*,4R*)-(±)- and (R*,3S*,4S*)-(±)-[(dppe)Pd(CHPhCHPhPPh)W(CO)5] have been determined. The configurations of the products are interpreted in terms of a transition state in which

  （E）-和（Z）-[W（CO）5（[HP]]）与[M（PR 3）2（C 2 H 4）] [M = Pd，（PR 3）2 = dppe（Ph 2 PCH 2 CH 2 PPh 2）; 已研究了M = Pt，PR 3 = PPh 3，并已通过NMR光谱法充分表征了以下产物[由M（PR 3）2蛙类插入到膦环中得到的结果]：（2 R *，3 S *，4 S*）-（±）-，（2 R *，3 S *，4 R *）-（±）-和（2 R *，3 S *，4 R *）-（±）-[（dppe）Pd （CHPhCHPhPPh）W（CO）5 ]；（2 S *，3 S *，4 S *）-（±）-，（2 S * 3 R * 4 R *）-（±）-和（2 S *，3 S *，4 R *）- （±）-[（Ph 3 P）2 Pt（CHPhCHPhPPh）W（CO）5 ]；和反式-（2 S *，3 S *，4 R *）-（±）-[（Ph
• Photochemical generation of bis(phosphine)palladium and bis(phosphine)platinum equivalents
  作者：Ralph S. Paonessa、Andrea L. Prignano、William C. Trogler

  DOI：10.1021/om00123a006

  日期：1985.4.1