bis(isopropylcyclopentadienyl)vanadium monochloride | 182759-24-6

• 英文名称: bis(isopropylcyclopentadienyl)vanadium monochloride
• CAS: 182759-24-6
• 化学式: C₁₆H₂₂ClV
• 分子量: 300.745
• InChiKey: XICCTIDECBZCMM-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  bis(isopropylcyclopentadienyl)vanadium monochloride 在 三氯化磷 作用下， 以 四氢呋喃 为溶剂， 以4.4 g的产率得到bis(isopropylcyclopentadienyl)vanadium dichloride
  参考文献：
  名称：

  Vanadocene complexes of amino acids bearing functional group in the side chain

  摘要：

  Reaction of Cp2VCl2 with alpha-amino acids bearing functional group in the side chain gives N,O-chelate complexes [Cp2V(N,O-aa)]Cl (aa = ser, thr, asp, glu, asn, gin, lys, arg). These complexes were studied by spectroscopic methods (ESR, IR and Raman). All prepared complexes contain amino acid ligand bonded via oxygen atom of carboxylic group and nitrogen atom of amino group in alpha-position giving five-membered chelate ring. We have observed that hydroxy, amine, carboxylic, amide and guanidinium groups present in alpha-amino acid ligand are not able to coordinate to the central vanadium atom. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2013.05.020
• 作为产物：
  描述：

  V(acac)3 、 1-异丙基-1,3-环戊二烯 在 甲基氯化镁 作用下， 以 四氢呋喃 为溶剂， 反应 1.75h， 生成 bis(isopropylcyclopentadienyl)vanadium monochloride
  参考文献：
  名称：

  Vanadocene complexes of amino acids bearing functional group in the side chain

  摘要：

  Reaction of Cp2VCl2 with alpha-amino acids bearing functional group in the side chain gives N,O-chelate complexes [Cp2V(N,O-aa)]Cl (aa = ser, thr, asp, glu, asn, gin, lys, arg). These complexes were studied by spectroscopic methods (ESR, IR and Raman). All prepared complexes contain amino acid ligand bonded via oxygen atom of carboxylic group and nitrogen atom of amino group in alpha-position giving five-membered chelate ring. We have observed that hydroxy, amine, carboxylic, amide and guanidinium groups present in alpha-amino acid ligand are not able to coordinate to the central vanadium atom. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2013.05.020