| 1009321-15-6

• CAS: 1009321-15-6
• 化学式: C₁₈H₂₁Cl₂CuN₃O
• 分子量: 429.836
• InChiKey: PZRVUHZUQNLFGP-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  N-[(3,5-dimethylpyrazol-1-yl)methyl]-N-(furan-2-ylmethyl)-1-phenylmethanamine 、 copper dichloride 以 四氢呋喃 为溶剂， 以99%的产率得到
  参考文献：
  名称：

  N-tripodal ligands to generate copper catalysts for the syndiotactic polymerization of methyl-methacrylate: Crystal structures of copper complexes

  摘要：

  A library of N-tripodal ligands, based on a central nitrogen atom connected to three different functionalized arms, was investigated via a parallel approach for the polymerization of methyl-methacrylate (MMA) in presence of late transition metal salts. Copper salts CuCl2 and Cu(OAC)(2) in combination with N-(2-furanylmethyl)-N-(1-3,5-dimetliyi-1H-pyrazolylmetliyl)-N- (phenylmethyl)amine were detected as efficient catalysts for the syndiotactic polymerization of MMA ([rr] up to 78%). Kinetic studies and X-ray structures of the best catalysts were reported. (C) 2007 Published by Elsevier B.V.

  DOI：

  10.1016/j.jorganchem.2007.11.010