trans,trans-[Cl(PBu3)2PdCCC6H4]2 | 957829-45-7

• 英文名称: trans,trans-[Cl(PBu3)2PdCCC6H4]2
• CAS: 957829-45-7
• 化学式: C₆₄H₁₁₆Cl₂P₄Pd₂
• 分子量: 1293.27
• InChiKey: NDHSASMCGHIFAI-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  trans,trans-[Cl(PBu3)2PdCCC6H4]2 、 potassium thioacetate 以 CH₂Cl₂ 为溶剂， 以95%的产率得到trans,trans-[CH3C(O)S(PBu3)2PdCCC6H4]2
  参考文献：
  名称：

  Self-Assembled Monolayers Based on Pd-Containing Organometallic Thiols: Preparation and Structural Characterization

  摘要：

  Multilayers and self-assembled monolayers of on-purpose-prepared organometallic thiolates, trans-[Pd(PBu3)(2)(SCOCH3)(2)], trans-[(C6H5C C)Pd(PBu3)(2)(SCOCH3)], and trans, trans-[(CH3COS)Pd(PBu3)(2)-(C C-C6H4-C6H4-C C)(PBu3)(2)Pd(SCOCH3)] Were deposited onto gold surfaces. High-resolution X-ray photoelectron spectroscopy and near-edge X-ray absorption fine structure measurements allowed us to assess the anchoring of the organometallic thiols onto gold substrates; the interaction occurring at the interface; and their molecular orientation oil the surface with tilt angles of about 30 degrees-40 degrees, depending on. the investigated molecule. The molecule packing density/coverage was also assessed.

  DOI：

  10.1021/jp904865k
• 作为产物：
  描述：

  4,4'-二乙炔基联苯 、 bis(tributylphosphine)dichloropalladium(II) 以 not given 为溶剂， 生成 trans,trans-[Cl(PBu3)2PdCCC6H4]2
  参考文献：
  名称：

  Self-Assembled Monolayers Based on Pd-Containing Organometallic Thiols: Preparation and Structural Characterization

  摘要：

  Multilayers and self-assembled monolayers of on-purpose-prepared organometallic thiolates, trans-[Pd(PBu3)(2)(SCOCH3)(2)], trans-[(C6H5C C)Pd(PBu3)(2)(SCOCH3)], and trans, trans-[(CH3COS)Pd(PBu3)(2)-(C C-C6H4-C6H4-C C)(PBu3)(2)Pd(SCOCH3)] Were deposited onto gold surfaces. High-resolution X-ray photoelectron spectroscopy and near-edge X-ray absorption fine structure measurements allowed us to assess the anchoring of the organometallic thiols onto gold substrates; the interaction occurring at the interface; and their molecular orientation oil the surface with tilt angles of about 30 degrees-40 degrees, depending on. the investigated molecule. The molecule packing density/coverage was also assessed.

  DOI：

  10.1021/jp904865k