bis(2-phenyl-pyridine)(5-chloromethylcarbonylamino-1,10-phenanthroline)iridium(III) hexafluorophosphate | 1314905-17-3

• 英文名称: bis(2-phenyl-pyridine)(5-chloromethylcarbonylamino-1,10-phenanthroline)iridium(III) hexafluorophosphate
• CAS: 1314905-17-3
• 化学式: C₃₆H₂₆ClIrN₅O*F₆P
• 分子量: 917.273
• InChiKey: KGYMBWIKVNUUDB-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  2-氨甲基吡啶 、 bis(2-phenyl-pyridine)(5-chloromethylcarbonylamino-1,10-phenanthroline)iridium(III) hexafluorophosphate 在 KI 、 triethylamine 作用下， 以 四氢呋喃 为溶剂， 以82%的产率得到
  参考文献：
  名称：

  A phosphorescent chemosensor for Cu2+ based on cationic iridium(III) complexes

  摘要：

  A cationic phosphorescent iridium complex 1 was synthesized, which can selectively detect Cu2+ confirmed by the luminescence spectra titration. In the presence of Cu2+, the obvious decrease of the luminescence intensity at 600 nm was investigated. The complex has been shown to display high selectivity for Cu2+ over other metal ions. The strong selective coordination interaction with Cu2+ is responsible for the significant change of the luminescence spectra, which is further confirmed by ESI-MS. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2011.11.006
• 作为产物：
  描述：

  六氟磷酸钾 、 [iridium(III)(μ-chloro)(2-phenylpyridine)2]2 、 2-chloro-N-(1,10-phenanthrolin-5-yl)acetamide 以 甲醇 、 二氯甲烷 为溶剂， 以70%的产率得到bis(2-phenyl-pyridine)(5-chloromethylcarbonylamino-1,10-phenanthroline)iridium(III) hexafluorophosphate
  参考文献：
  名称：

  A phosphorescent chemosensor for Cu2+ based on cationic iridium(III) complexes

  摘要：

  A cationic phosphorescent iridium complex 1 was synthesized, which can selectively detect Cu2+ confirmed by the luminescence spectra titration. In the presence of Cu2+, the obvious decrease of the luminescence intensity at 600 nm was investigated. The complex has been shown to display high selectivity for Cu2+ over other metal ions. The strong selective coordination interaction with Cu2+ is responsible for the significant change of the luminescence spectra, which is further confirmed by ESI-MS. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2011.11.006