dichlorobis[2-(o-tolyliminiomethyl)phenolato-O]zinc(II) | 316382-59-9

• 英文名称: dichlorobis[2-(o-tolyliminiomethyl)phenolato-O]zinc(II)
• CAS: 316382-59-9；73969-45-6
• 化学式: C₂₈H₂₆Cl₂N₂O₂Zn
• 分子量: 558.823
• InChiKey: RXUKKAPYBXSDHP-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (6E)-6-[[(2-甲基苯基)氨基]亚甲基]环己-2,4-二烯-1-酮 、 zinc(II) chloride 以 甲醇 为溶剂， 生成 dichlorobis[2-(o-tolyliminiomethyl)phenolato-O]zinc(II)
  参考文献：
  名称：

  Dichlorobis[2-(o-tolyliminiomethyl)phenolato-O]zinc(II)

  摘要：

  In the mononuclear title compound, [ZnCl2(C14H13NO)(2)], the Zn-II ion is located on a twofold axis of the monoclinic space group so that the whole molecule has a twofold symmetry. The Zn-II ion has a tetrahedral coordination consisting of two chlorine ions and the O atoms of the ligands. The coordination angles around zinc have values between 102.89 (8) (O-Zn-O) and 115.83 (5)degrees (Cl-Zn-O). The Zn-O and Zn-Cl bond lengths are 1.977 (2) and 2.2401 (7) Angstrom, respectively. There are intra- and intermolecular hydrogen bonds in the structure.

  DOI：

  10.1107/s0108270100009008