[PdCl2(1,2-diferrocenyl-3,4-diphosphinidenecyclobutene)] | 855791-32-1

• 英文名称: [PdCl2(1,2-diferrocenyl-3,4-diphosphinidenecyclobutene)]
• CAS: 855791-32-1
• 化学式: C₆₀H₇₆Cl₂Fe₂P₂Pd
• 分子量: 1148.23
• InChiKey: MWYFMMLYSAAEBB-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  双(乙腈)氯化钯(II) 、 1,2-diferrocenyl-3,4-diphosphinidenecyclobutene methylenedichloride monosolvate 以 四氢呋喃 为溶剂， 以99%的产率得到[PdCl2(1,2-diferrocenyl-3,4-diphosphinidenecyclobutene)]
  参考文献：
  名称：

  Preparation and Properties of 1,2-Diferrocenyl-Substituted 3,4-Diphosphinidenecyclobutenes and Their Complexes:  The First Application of a Diphosphinidenecyclobutene Unit as a Linker of Functional Moieties

  摘要：

  Compounds with two ferrocenyl units connected with 3,4-diphosphinidenecyclobutene (DPCB) linkers at the 1,2-positions (1) and their transition metal chelate complexes (2) were prepared, and the spectroscopic and electrochemical properties were studied. The compounds were examined by cyclic voltammetry, and Delta E(1/2) values (the separation between successive Fe(2+)/Fe(3+) oxidation potentials) were determined. Being fully conjugated with DPCB linkers, those compounds demonstrated electrochemical communication: the Cr(CO)(4) complex of 1 (2Cr) showed a strong interaction (Delta E(1/2) = 350 mV), whereas PdCl(2) and PtCl(2) complexes of 1 (2Pd and 2Pt) displayed a decreased interaction compared to that of 1.

  DOI：

  10.1021/om0500772