| 850354-07-3

• CAS: 850354-07-3
• 化学式: C₄₈H₄₂ClFeNOP₂Ru
• 分子量: 903.185
• InChiKey: ISRSTISHDHYFFH-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  、 2,6-bis(diphenylphosphinomethyl)pyridine 以 二氯甲烷 为溶剂， 以86%的产率得到
  参考文献：
  名称：

  Synthesis and Characterization of (CHCH)₃-Bridged Heterobimetallic Ferrocene−Ruthenium Complexes

  摘要：

  The complex Fc(CH=CH)(2)C equivalent to C-TMS (Fc = ferrocenyl) was obtained from Wittig olefination of FcCH(2)PPh(3)Br with TMS-C equivalent to CCH=CHCHO in THF. The conjugated monometallic diene can be desilylated to give Fc(CH=CH)(2)C equivalent to CH, which reacted with RuHCl(CO)(PPh3)(3) to produce Fc(CH=CH)(3)RuCl(CO)(PPh3)(2). Treatment of the latter complex,with PMe3, 4-phenylpyridine (PbPy), 2,6-(Ph2PCH2)(2)C5H3N (PMP), and KTp (Tp = hydridotris(pyrazolyl)borate) gave Fc(CH=CH)(3)RuCl(CO)(PMe3)(3), Fc(CH=CH)(2)RuCl(CO)(PhPy)(PPh3)(2), Fc(CH= CH)(3)RuCl(CO)(PMP), and Fc(CH=CH)(3)RuTp(CO)(PPh3), respectively. The structures of Fc(CH=CH)(2)C equivalent to CH and Fc(CH=CH)(3)RuCl(CO)(PMe3)(3) have been confirmed by X-ray diffraction.

  DOI：

  10.1021/om0490637