1-[chloro(ethyl)(methyl)silyl]-2-(chloro(diethyl)silyl)ethane | 90722-98-8

• 英文名称: 1-[chloro(ethyl)(methyl)silyl]-2-(chloro(diethyl)silyl)ethane
• 英文别名: 1-(Diethyl-chlorsilyl)-2-(methyl-ethyl-chlorsilyl)-ethan；1-[Chloro(ethyl)methylsilyl]-2-(chlorodi-ethylsilyl)ethane；chloro-[2-[chloro(diethyl)silyl]ethyl]-ethyl-methylsilane
• CAS: 90722-98-8
• 化学式: C₉H₂₂Cl₂Si₂
• 分子量: 257.351
• InChiKey: ZSPHREMXFDAPOB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.04
• 重原子数：
  13
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1-[chloro(ethyl)(methyl)silyl]-2-(chloro(diethyl)silyl)ethane 在 吡啶 、 氯化亚砜 作用下， 生成 1,10-Dichlor-4,7,7-triaethyl-4-methyl-4,7-disila-decandiin-(2,8)
  参考文献：
  名称：

  Smetankina,N.P. et al., Journal of general chemistry of the USSR, 1966, vol. 36, p. 1997 - 2000

  摘要：

  DOI：
• 作为产物：
  描述：

  二乙基氯硅烷 、 乙烯基乙基甲基氯硅烷 在 dihydrogen hexachloroplatinate 作用下， 以 异丙醇 为溶剂， 生成 1-[chloro(ethyl)(methyl)silyl]-2-(chloro(diethyl)silyl)ethane
  参考文献：
  名称：

  Kuznetsova,V.P. et al., Journal of general chemistry of the USSR, 1964, vol. 34, p. 1875 - 1878

  摘要：

  DOI：

文献信息

• Synthesis of unsymmetrical 1,2-bis(diorganochlorosilyl)ethanes
  作者：V. G. Lakhtin、S. P. Knyazev、L. E. Gusel’nikov、E. N. Buravtseva、N. A. Kuyantseva、I. A. Zalomnova、L. A. Parshkova、V. G. Bykovchenko、A. V. Kisin、E. A. Chernyshev

  DOI：10.1134/s1070363208090053

  日期：2008.9

  Unsymmetrical 1,2-bis(diorganylsilyl)ethanes were synthesized by two procedures. Hydrosilylation of chloro(vinyl)silanes were used to obtain compounds of the general formula ClMe2SiCH2CH2SiRMeCl with different substituents (R = Et, Vin, Ph) on the silicon atom. Chlorodealkylation of 1,2-bis(trialkylsilyl)ethanes gave compounds of the general formula ClAlk(2)SiCH(2)CH(2)SiAlk(2)Cl (Alk = Me, Et, Pr). It is established that the latter reaction provides high yields only with Me- and Et-substituted compounds, whereas Pr-substituted products are formed in poor yields. The mechamism of this reaction based on quantum-chemical calculations is offered.