[(Z,Z-1,5-cyclooctadiene)Rh(N,N-di-[(1-methyl-1H-2-imidazolyl)methyl]amine)]PF6 | 496789-14-1

• 英文名称: [(Z,Z-1,5-cyclooctadiene)Rh(N,N-di-[(1-methyl-1H-2-imidazolyl)methyl]amine)]PF6
• CAS: 496789-14-1
• 化学式: C₁₈H₂₇N₅Rh*F₆P
• 分子量: 561.316
• InChiKey: ACJZIYZRZUBYKD-ONEVTFJLSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  ammonium hexafluorophosphate 、 bis<(1-methylimidazol-2-yl)methyl>amine 、 chloro(1,5-cyclooctadiene)rhodium(I) dimer 以 甲醇 为溶剂， 以59.3%的产率得到[(Z,Z-1,5-cyclooctadiene)Rh(N,N-di-[(1-methyl-1H-2-imidazolyl)methyl]amine)]PF6
  参考文献：
  名称：

  Amido-bridged dinuclear rhodium(I) complexes by deprotonation of mononuclear rhodium(I) amine complexes

  摘要：

  The preparation of a series of new amido bridged binuclear complexes [(N-N-N)Rh-2(1) (cod)(2)] (cod = Z,Z- 1,5-cyclooctadiene), [(N-N-N)Rh-2(1) (hed)(2)] (hed = 1,5-hexadiene) and [(N-N-N)Rh-2(1) (CO)(4)] is reported. These complexes contain chelating imidazoleamido-imidazole, pyridine-amido-pyridine and pyridine-amido-pyrrolate ligands (N-N-N). The cod complexes have been prepared through deprotonation of their mononuclear amine precursors [(N-HN-N)Rh-1(cod)] in the presence of [Rh-1(cod)](+). Reaction of the binuclear complexes [(N-N-N)Rh-2(1) (cod)(2)] with CO results in the complexes [(N-N-N)Rh-2(1) (CO)(4)]. For N-N-N= chelating imidazole-amido-imidazole ligand, the X-ray structures of [(N-N-N)Rh-2(1)(cod)(2)], [(N-N-N)Rh-2(1)(CO)(4)], and their mononuclear amine precursor [(N-HN-N)Rh-1(cod)] are reported. Electrochemical oxidation of the complexes is related to the relative donor strength of the N-ligands. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)01030-7