trans-dichlorobis(2,2-dimethylpropane-1,3-diamine-κ2N,N')chromium(III) perchlorate | 170659-44-6

• 英文名称: trans-dichlorobis(2,2-dimethylpropane-1,3-diamine-κ2N,N')chromium(III) perchlorate
• CAS: 170659-44-6
• 化学式: C₁₀H₂₈Cl₂CrN₄*ClO₄
• 分子量: 426.712
• InChiKey: QOPBQQROFNUYRQ-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  高氯酸 、 trans-dichlorobis(2,2-dimethylpropane-1,3-diamine-κ2N,N')chromium(III) perchlorate 、 水 、 氢溴酸 在 NaOH 作用下， 以 水 为溶剂， 生成 bis[trans-dibromobis(2,2-dimethylpropane-1,3-diamine-κ2N,N')chromium(III)] dibromide hydrogen perchlorate hexahydrate
  参考文献：
  名称：

  Bis[trans-dibromo(2,2-dimethylpropane-1,3-diamine-κ²N,N′)chromium(III)] dibromide hydrogen perchlorate hexahydrate

  摘要：

  In the title compound, [CrBr2(C5H14N2)(2)](2)Br-2.HClO4.6H(2)O, there are two independent Cr-III complex cations which are conformational isomers of each other. The Cr atoms lie respectively on a center of symmetry and on a mirror plane and have octahedral environments, coordinated by the N atoms of two 2,2-dimethylpropane-1,3-diamine ligands and by two Br atoms in trans positions. The Cr-N and Cr-Br bond lengths are in the ranges 2.078 (3)-2.089 (3) and 2.4495 (9)-2.5017 (9) Angstrom, respectively. The crystal structure consists of two Cr-III complex cations, two Br- anions, a (ClO4)(-) anion and an [H13O6](+) hydrogen-bonded cluster cation.

  DOI：

  10.1107/s0108270102018231