| 350802-90-3

• CAS: 350802-90-3
• 化学式: C₂₁H₁₇FeN₃
• 分子量: 367.233
• InChiKey: PBJDDGRQNVZTSQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  tetrakis(acetonitrile)copper(I)tetrafluoroborate 、 以 氘代乙腈 为溶剂， 生成
  参考文献：
  名称：

  Synthesis and Properties of the First Ferrocene-Functionalized Ligand in Which All the Donor Atoms Are Cyclopentadienyl-Conjugated

  摘要：

  The synthesis of a new type of ferrocene-functionalized ligand for transition-metal binding is described. The ligand is the first electroactive ferrocene receptor to possess complete conjugation between all the donor atoms and the cyclopentadienyl moiety to which they are attached. (1)H and natural-abundance (15)N NMR studies indicate that a complex of 2:1 stoichiometry (ligand:Cu(+) ion) is formed, in which the Cu+ ion is surrounded tetrahedrally by a bipyridyl-like pair of donor nitrogen atoms from each of two ligands, Electrochemical data show that the conjugation of each of the donor atoms with the cyclopentadienyl ring results in an enhanced electrochemical response of the ferrocene moiety to Cu+ ion binding relative to a similar ligand in which the donor atoms are not conjugated with the cyclopentadienyl ring.

  DOI：

  10.1021/om0007567
• 作为产物：
  描述：

  2-二吡啶基酮 、 aminoferrocene 以 四氢呋喃 为溶剂， 以92%的产率得到
  参考文献：
  名称：

  Synthesis and Properties of the First Ferrocene-Functionalized Ligand in Which All the Donor Atoms Are Cyclopentadienyl-Conjugated

  摘要：

  The synthesis of a new type of ferrocene-functionalized ligand for transition-metal binding is described. The ligand is the first electroactive ferrocene receptor to possess complete conjugation between all the donor atoms and the cyclopentadienyl moiety to which they are attached. (1)H and natural-abundance (15)N NMR studies indicate that a complex of 2:1 stoichiometry (ligand:Cu(+) ion) is formed, in which the Cu+ ion is surrounded tetrahedrally by a bipyridyl-like pair of donor nitrogen atoms from each of two ligands, Electrochemical data show that the conjugation of each of the donor atoms with the cyclopentadienyl ring results in an enhanced electrochemical response of the ferrocene moiety to Cu+ ion binding relative to a similar ligand in which the donor atoms are not conjugated with the cyclopentadienyl ring.

  DOI：

  10.1021/om0007567