[(tript)AlCl2(OEt2)] | 682915-11-3

• 英文名称: [(tript)AlCl2(OEt2)]
• CAS: 682915-11-3
• 化学式: C₂₄H₂₃AlCl₂O
• 分子量: 425.334
• InChiKey: VJRCFJXVPKSUEK-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  三氯化铝 、 乙醚 、 9-三苯基锂 以 乙醚 、 甲苯 为溶剂， 以63%的产率得到[(tript)AlCl2(OEt2)]
  参考文献：
  名称：

  9-Triptycenyl complexes of group 13 and 15 halides and hydrides

  摘要：

  The reactions of 9-lithiotriptycene with AlCl3, GaCl3 and InBr3 have been carried out and have yielded the complexes, [(tript)AlCl2(OEt2)], [(tript)GaCl2(THF)] and [(tript)InBr(mu-Br)(2)Li(OEt2)(2)], tript=9-triptycenyl. The latter two complexes have been structurally characterised. The corresponding reactions of 9-lithiotriptycene with ECl3 (E = P, As, Sb or Bi) afforded the complexes, [(tript)ECl2], of which all but the phosphorus compound have been crystallographically authenticated. In addition, the high yield syntheses of the thermally stable primary pnictanes [(tript)EH2] (E = As, Sb) have been achieved by reaction of the relevant halide complex with LiAlH4. The X-ray crystal structure of the antimony hydride complex is reported. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2003.12.014