| 1011490-82-6

• CAS: 1011490-82-6
• 化学式: C₁₈H₄₄Cl₂O₂RuSi₄Te₂
• 分子量: 832.064
• InChiKey: KILFHXKTCKKISC-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  dicarbonyldichlororuthenium 、 Bis<(trimethylsilyl)methyl>telluran 以 四氢呋喃 为溶剂， 以42%的产率得到
  参考文献：
  名称：

  Preparation and structural characterization of [RuCl2(CO)2{Te(CH2SiMe3)2}2] and [RuCl2(CO){Te(CH2SiMe3)2}3]

  摘要：

  The objective of the present work was to synthesize mononuclear ruthenium complex [RuCl2(CO)(2){Te(CH2SiMe3)(2)}(2)] (1) by the reaction of Te(CH2SiMe3)(2) and [RuCl2(CO)(3)](2). However, the stoichiometric reaction affords a mixture of 1 and [RuCl2(CO){Te(CH2SiMe3)(2))(3)] (2). The X-ray structures show the formation of the cis(CI), cis(C), trans(Te) isomer of I and the cis(CI), mer(Te) isomer of 2. The Te-125 NMR spectra of the complexes are reported. The complex distribution depends on the initial molar ratio of the reactants. With an excess of [RuCl2(CO)(3)](2) only I is formed. In addition to the stoichiometric reaction, a mixture of I and 2 is observed even when using an excess of Te(CH2SiMe3)(2-) Complex 1 is, however, always the main product. In these cases the Te-125 NMR spectra of the reaction solution also indicates the presence of unreacted ligand. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.11.026