| 139431-12-2

• CAS: 139431-12-2
• 化学式: AgF*AuF₄
• 分子量: 399.827
• InChiKey: CJTHYFDTCGMYID-UHFFFAOYSA-I

计算性质

• 辛醇/水分配系数(LogP)：
  -1.32
• 重原子数：
  7.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  silver tetrafluoroaurate(III) 、 氢氟酸 以 氢氟酸 为溶剂， 以0%的产率得到silver(I) hexafluoroaurate(V)
  参考文献：
  名称：

  Structural Features of Ag[AuF₄] and Ag[AuF₆] and the Stuctural Relationship of Ag[AgF₄]₂ and Au[AuF₄]₂ to Ag[AuF₄]₂

  摘要：

  Synchrotron radiation X-ray powder diffraction data (SPDD) have been obtained for Ag[AgF4](2), Au[AuF4](2), Ag[AuF4], and Ag[AuF4](2). Ag[AgF4](2) and Au[AuF4](2) are isostructural with Ag[AuF4](2), space group (SG) P2(l)/n, Z = 2, with the following: for Ag[AgF4](2) a = 5.04664(8), b = 11.0542(2), c = 5.44914(9) Angstrom, beta 97.170(2)degrees; for Au[AuF4](2) a = 5.203(2), b = 11.186(3), c = 5.531(2) Angstrom, beta 90.55(2)degrees. The structure of Ag[AgF4](2) was refined successfully (SPDD) applying the Rietveld method, yielding the following interatomic distances (Angstrom): Ag-II-F = 2.056(12), 2.200(13), 2.558(13); Ag-III-F = two at 1.846(12), others = 1.887(12), 1.909(13), 2.786(12), 2.796(12), 2.855(12). AgAuF4, like other AA'F-4 salts (A = Na-Rb; A' = Ag, Au), crystallizes in the KBrF4 structure type, SG I4/mcnn (140), Z = 4 with a = 5.79109(6), c 10.81676(7) Angstrom. SPDD gave (in Angstrom) four Au-III-F = 1.89(1) and eight Ag-I-F = 2.577(7). SPDD for AgAuF6 confirmed that it has the LiSbF6 structure, 15.0451(6) Angstrom. SG R (3) over bar, Z = 3, with a = 5.2840(2), c = 15.0451(6) Angstrom.

  DOI：

  10.1021/ic991178t

文献信息

• Structural and magnetic properties of some AgF+ Salts
  作者：William J. Casteel、George Lucier、Rika Hagiwara、Horst Borrmann、Neil Bartlett

  DOI：10.1016/s0022-4596(05)80300-7

  日期：1992.1