Co(tetrazol-1-yl-tris(hydroxymethyl)methane)2Br2*2H2O | 1363414-20-3

• 英文名称: Co(tetrazol-1-yl-tris(hydroxymethyl)methane)2Br2*2H2O
• CAS: 1363414-20-3
• 化学式: C₁₀H₂₄Br₂CoN₈O₈
• 分子量: 603.151
• InChiKey: FIJPEKUKWGONAM-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  水 、 氢溴酸 、 钴 、 tetrazol-1-yl-tris(hydroxymethyl)methane 以 甲醇 为溶剂， 以98%的产率得到Co(tetrazol-1-yl-tris(hydroxymethyl)methane)2Br2*2H2O
  参考文献：
  名称：

  Complexes of Co(II), Ni(II), and Cu(II) chlorides and bromides with tetrazol-1-yl-tris(hydroxymethyl)methane: Synthesis and structure

  摘要：

  The reactions of Co(II), Ni(II), and Cu(II) chlorides and bromides and their metallic powders with tetrazol-1-yl-tris(hydroxymethyl)methane (L) afforded new complexes ML(2)Hal(2) center dot mH(2)O(M = Co(II) or Ni(II), Hal = Cl-; M = Cu(II), Hal = Cl- or Br-, m = 0; and M = Co(II) or Ni(II), Hal = Br-, m = 2), MLnCl2 (M = Co(II) or Ni(II), n = 2 or 4; M = Cu(II), n = 2), and MLnBr2 center dot mH(2)O (M = Ni(II), n = 2, m = 2; M = Cu(II), n = 2, m = 0). The compositions and structures of the synthesized complexes were determined by elemental analysis, IR spectroscopy (50-4000 cm(-1)), and X-ray diffraction analysis. The introduction of a bulky substituent into position 1 of the tetrazole cycle was shown to exert almost no effect on the coordination mode but affected the composition and structure of the complexes.

  DOI：

  10.1134/s1070328412010010