[3]-ferrocenophan-2-(1-naphthylamin) | 424829-04-9

• 英文名称: [3]-ferrocenophan-2-(1-naphthylamin)
• CAS: 424829-04-9
• 化学式: C₂₃H₂₁FeN
• 分子量: 367.273
• InChiKey: YJDWQTGZWQOXQA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  盐酸 、 [3]-ferrocenophan-2-(1-naphthylamin) 、 5-(二乙氨基)-2-(亚硝基苯酚) 以 乙醚 、 乙醇 、 二氯甲烷 为溶剂， 以69%的产率得到
  参考文献：
  名称：

  Ultrafast intramolecular electron transfer from a ferrocene donor moiety to a nile blue acceptor

  摘要：

  The fastest electron transfer processes between molecular donor/acceptor systems have been observed for solvent to solute type reactions, where the number of solvent molecules participating could be high. This might explain the very short electron transfer times of less than or equal to 100 fs observed. Here the photo-induced electron transfer in a bridged donor/acceptor system was studied by femtosecond pump-probe spectroscopy with a time resolution of 15 fs. After photoexcitation of the acceptor (nile blue) an electron is transferred from the donor (ferrocene) with a time constant of 90 fs, i.e. close to fastest electron transfer times in the solute/solvent systems. (C) 2002 Published by Elsevier Science B.V.

  DOI：

  10.1016/s0009-2614(01)01395-1