[AgCl(2-methylimidazole)(PPh3)2] | 883992-35-6

• 英文名称: [AgCl(2-methylimidazole)(PPh3)2]
• 英文别名: [AgCl(imme)(PPh3)2]
• CAS: 883992-35-6
• 化学式: C₄₀H₃₆AgClN₂P₂
• 分子量: 750.008
• InChiKey: WCNSAAUQXHSJHE-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-甲基咪唑 、 AgCl(PPh3)3 以 乙醚 为溶剂， 以74%的产率得到[AgCl(2-methylimidazole)(PPh3)2]
  参考文献：
  名称：

  Synthesis, spectroscopy and structural characterization of silver(I) complexes containing unidentate N-donor azole-type ligands

  摘要：

  From the interaction between azole-type ligands L and AgX (X = NO3 or ClO4) or [AgX(PPh3)(n)] (X = Cl, n = 3; X = MeSO3. n = 2), new ionic mononuclear [Ag(L)(2)]X and [Ag(PPh3)(3)L][X] or neutral mono-([Ag(PPh3)(n)L(X)]) or di-nuclear ([{Ag(PPh3)(L)(mu-X)}(2)]) complexes have been obtained which have been characterized through elemental analysis, conductivity measurements, IR, H-1 NMR and, in some cases, also by (31)p{H-1} NMR spectroscopy, and single-crystal X-ray studies. Stoichiometries and molecular structures are dependent on the nature of the azole (steric hindrance and basicity), of the counter ion, and on the number of the P-donor ligands in the starting reactants. Solution data are consistent with partial dissociation of the complexes, occurring through breaking of both Ag-N and Ag-P bonds. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.10.016