| 316378-85-5

• CAS: 316378-85-5
• 化学式: C₃₅H₃₃Fe₃ISi
• 分子量: 776.178
• InChiKey: ZYICERFKQDUXII-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  在 n-butyllithium 、 H₂O 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 生成
  参考文献：
  名称：

  Communication between Co₂(CO)₄dppm Units via Polyferrocenylalkyne Linkages

  摘要：

  The synthesis and characterization of a family of ethynylbi- and ethynylterferrocenyls, I-Fc(2)C=CR, Fc(2)C=CR, and Fc(2)(C=CR)(2) (R = Fc, SiMe3), I-Fc(3)C=CSiMe3, Fc(3)C=CSiMe3, Fc(3)(C=CSiMe3)(2), and their Co-2(CO)(6) and Co-2(CO)(4)dppm complexes are described. The structure adopted by Fc(2){[Co-2(CO)(4)dppm C2SiMe3]}(2) minimizes the steric interactions between the biferrocene and dppm moieties. Electrochemical studies show that identical redox centers-ferrocenyl termini, Co-2(CO)(4)dppm units, or ferrocenyl groups in the core-communicate independently with each other.

  DOI：

  10.1021/om000493g
• 作为产物：
  描述：

  4-Cyclopenta-2,4-dien-1-ylidenecyclopentene;2-iodocyclopenta-1,3-diene;iron(2+) 、 三甲基乙炔基硅 在 bis-triphenylphosphine-palladium(II) chloride 、 copper diacetate 作用下， 以 further solvent(s) 为溶剂， 以22%的产率得到1,1'-bis(trimethylsilylethynyl)triferrocene
  参考文献：
  名称：

  Communication between Co₂(CO)₄dppm Units via Polyferrocenylalkyne Linkages

  摘要：

  The synthesis and characterization of a family of ethynylbi- and ethynylterferrocenyls, I-Fc(2)C=CR, Fc(2)C=CR, and Fc(2)(C=CR)(2) (R = Fc, SiMe3), I-Fc(3)C=CSiMe3, Fc(3)C=CSiMe3, Fc(3)(C=CSiMe3)(2), and their Co-2(CO)(6) and Co-2(CO)(4)dppm complexes are described. The structure adopted by Fc(2){[Co-2(CO)(4)dppm C2SiMe3]}(2) minimizes the steric interactions between the biferrocene and dppm moieties. Electrochemical studies show that identical redox centers-ferrocenyl termini, Co-2(CO)(4)dppm units, or ferrocenyl groups in the core-communicate independently with each other.

  DOI：

  10.1021/om000493g