| 210307-51-0

• CAS: 210307-51-0
• 化学式: C₄₈H₅₂Cl₂N₆O₂P₂Pd₂
• 分子量: 1090.67
• InChiKey: SKOBPIRNZCOISF-JONACIMVSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 silver perchlorate 以 丙酮 为溶剂， 生成
  参考文献：
  名称：

  Cylometallated semicarbazone complexes of palladium(II). Crystal and molecular structure of [{Pd[C6H4C(Et)NN(H)C(O)NH2]}2(μ-Ph2P(CH2)3PPh2)][ClO4]2

  摘要：

  Treatment of the semicarbazones 4-MeC6H4C(Me)=NN(H)C(=O)NH2 a, 3,4-Me2C6H3C(Me)=NN(H)C(=O)NH2 b and C6H5C(Et)=NN(H)C(=O)NH2 c, gave the [C,N,O] cyclometallated compounds [Pd{4-MeC6H3C(Me)=NN(H)C(=O)NH2}(Cl)] 1a, [Pd{3,4-Me2C6H2C(Me)=NN(H)C(=O)NH2}(Cl)] 1b and [Pd{C6H4C(Et)=NN(H)C(=O)NH2}(Cl)] 1c, after C-H activation. Treatment of compounds 1a, 1b, and 1c with silver perchlorate followed by treatment with tertiary diphosphine ligands gave the dinuclear [C,N,O] cyclometallated compounds [{Pd[4-MeC6H3C(Me)=NN(H)C(=O)NH2]}(2)(mu-L)][ClO4](2) 2a-7a, [{Pd[3,4-Me2C6H2C(Me)=NN(H)C(=O)NH2]}(2)(mu-L)][ClO4](2) 2b-7b, [{Pd[C6H4C(Et)=NN(H)C(=O)NH2]}(2)(mu-L)][ClO4](2) 2c-7c, [L = Ph2P(CH2)(4)PPh2 (dppb), Ph2P(CH2)(3)PPh2 (dppp), Ph2P(CH2)(2)PPh2 (dppe), trans-Ph2PCH=CHPPh2 (trans-dppe), Ph2PC(=CH2)PPh2 (vdpp) and Ph2PCH2PPh2 (dppm)] as 1:2 electrolytes. Reaction of 1a and 1c with diphosphines gave the dinuclear [C,N] cyclometallated compounds [{Pd[4-MeC6H3C(Me)=NN(H)C(=O)NH2](Cl)}(2)(mu-L)] 8a, 9a, [{Pd[C6H4C(Et)=NN-(H)C(=O)NH2](Cl)}(2)(mu-L)] 8c, 9c, [L = Ph2P(CH2)(3)PPh2 (dppp) and Ph2P(CH2)(4)PPh2 (dppb)]. The complexes were characterised by their elemental analysis (C,H,N) and by IR and P-31{H-1} and H-1-NMR data, and [{Pd[C6H4C(Et)=NN(H)C(=O)NH2]}(2)(mu-Ph2P(CH2)(3)PPh2)][ClO4](2) (3c) was characterised crystallographically. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(97)00668-2
• 作为产物：
  描述：

  propiophenone semicarbazone 在 sodium acetate 作用下， 以 甲醇 、 丙酮 为溶剂， 生成
  参考文献：
  名称：

  Cylometallated semicarbazone complexes of palladium(II). Crystal and molecular structure of [{Pd[C6H4C(Et)NN(H)C(O)NH2]}2(μ-Ph2P(CH2)3PPh2)][ClO4]2

  摘要：

  Treatment of the semicarbazones 4-MeC6H4C(Me)=NN(H)C(=O)NH2 a, 3,4-Me2C6H3C(Me)=NN(H)C(=O)NH2 b and C6H5C(Et)=NN(H)C(=O)NH2 c, gave the [C,N,O] cyclometallated compounds [Pd{4-MeC6H3C(Me)=NN(H)C(=O)NH2}(Cl)] 1a, [Pd{3,4-Me2C6H2C(Me)=NN(H)C(=O)NH2}(Cl)] 1b and [Pd{C6H4C(Et)=NN(H)C(=O)NH2}(Cl)] 1c, after C-H activation. Treatment of compounds 1a, 1b, and 1c with silver perchlorate followed by treatment with tertiary diphosphine ligands gave the dinuclear [C,N,O] cyclometallated compounds [{Pd[4-MeC6H3C(Me)=NN(H)C(=O)NH2]}(2)(mu-L)][ClO4](2) 2a-7a, [{Pd[3,4-Me2C6H2C(Me)=NN(H)C(=O)NH2]}(2)(mu-L)][ClO4](2) 2b-7b, [{Pd[C6H4C(Et)=NN(H)C(=O)NH2]}(2)(mu-L)][ClO4](2) 2c-7c, [L = Ph2P(CH2)(4)PPh2 (dppb), Ph2P(CH2)(3)PPh2 (dppp), Ph2P(CH2)(2)PPh2 (dppe), trans-Ph2PCH=CHPPh2 (trans-dppe), Ph2PC(=CH2)PPh2 (vdpp) and Ph2PCH2PPh2 (dppm)] as 1:2 electrolytes. Reaction of 1a and 1c with diphosphines gave the dinuclear [C,N] cyclometallated compounds [{Pd[4-MeC6H3C(Me)=NN(H)C(=O)NH2](Cl)}(2)(mu-L)] 8a, 9a, [{Pd[C6H4C(Et)=NN-(H)C(=O)NH2](Cl)}(2)(mu-L)] 8c, 9c, [L = Ph2P(CH2)(3)PPh2 (dppp) and Ph2P(CH2)(4)PPh2 (dppb)]. The complexes were characterised by their elemental analysis (C,H,N) and by IR and P-31{H-1} and H-1-NMR data, and [{Pd[C6H4C(Et)=NN(H)C(=O)NH2]}(2)(mu-Ph2P(CH2)(3)PPh2)][ClO4](2) (3c) was characterised crystallographically. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(97)00668-2