[Et2GaO(C6H4)CMe=NCH2-]2 | 1175120-18-9

• 英文名称: [Et2GaO(C6H4)CMe=NCH2-]2
• CAS: 1175120-18-9
• 化学式: C₂₆H₃₈Ga₂N₂O₂
• 分子量: 550.046
• InChiKey: WPHVNEFDYTUOGJ-CKVJLEMISA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  N,N'-二(2-羟基-alpha-甲基苄亚基)乙二胺 、 triethylgallium diethyl ether adduct 以 苯 为溶剂， 以96%的产率得到[Et2GaO(C6H4)CMe=NCH2-]2
  参考文献：
  名称：

  Diorgano-gallium and -indium complexes with salen ligands: Synthesis, characterization, crystal structure and C–C coupling reactions

  摘要：

  The reactions of triorgano-gallium and -indium etherate with salen ligands in benzene afforded complexes of the type [R2MOC6H4CR'=NCH2-](2), (R/M/R' = Me/Ga/H (1), Et/Ga/H (2), Me/In/H (3), Et/Ga/Me (4)) in nearly quantitative yields. These complexes have been characterized by elemental analysis, IR, UV-Vis, NMR (H-1 and C-13{H-1}) and mass spectral data. The organogallium complexes showed photoluminescence in blue-green region. The complex, [(Me2Ga)(2)(O-(C6H4)CH=N-CH2-)(2)] on recrystallization from benzene-hexane and dichloromethane gave orthorhombic and monoclinic forms, respectively. Both the forms are dimeric with gallium atoms acquiring a distorted tetrahedral configuration defined by two methyl groups, phenolate oxygen and azomethene nitrogen. The complexes [(Me2Ga)(2)(O-(C6H4)CH=N-CH2-)(2)] and [(Me2In)(2)(O-(C6H4)CH=N-CH2-)(2)] have been employed as alkylating agent for C-C coupling reaction of 1-bromonaphthalene in presence of PdCl2(PPh3)(2). (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2009.03.029