9-ferrocenyl-3-methyl-3,7,8-triazabicyclo[4.3.0]non-6(7)-ene | 356041-20-8

• 英文名称: 9-ferrocenyl-3-methyl-3,7,8-triazabicyclo[4.3.0]non-6(7)-ene
• 英文别名: 9-ferrocenyl-3-methyl-3,7,8-triazabicyclo[4.3.0]non-6-ene
• CAS: 356041-20-8
• 化学式: C₁₇H₂₁FeN₃
• 分子量: 323.221
• InChiKey: HQFBAPRVOMRXRU-NJDKGTEJSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  9-ferrocenyl-3-methyl-3,7,8-triazabicyclo[4.3.0]non-6(7)-ene 、 乙酸酐 在 Na₂CO₃ 作用下， 以 乙酸酐 为溶剂， 以71%的产率得到8-acetyl-9-ferrocenyl-3-methyl-3,7,8-triazabicyclo[4.3.0]non-6-ene
  参考文献：
  名称：

  摘要：

  The reactions of E- and Z-isomeric 2-(ferrocenylmethylidene)quinuclidin-3-one, 1-methyl-3-(ferrocenylmethylidene)piperidin-4-one, and 2-(ferrocenylmethylidene)tropinone with hydrazine proceed stereospecifically to form the same diastereomeric polycyclic ferrocenyldihydropyrazoles regardless of the geometrical configuration of the starting alpha,beta -unsaturated ketones. The structure of the trans-diastereomer of 4-acetyl-3-ferrocenyl-1,4,5-triazatricyclo[5.2.2.0(2,6)]undec-5-ene was established by X-ray diffraction analysis.

  DOI：

  10.1023/a:1011375613460
• 作为产物：
  描述：

  Z-3-(ferrocenylmethylidene)-1-methylpiperidin-4-one 、 hydrazine hydrate 以 乙醇 为溶剂， 以70%的产率得到9-ferrocenyl-3-methyl-3,7,8-triazabicyclo[4.3.0]non-6(7)-ene
  参考文献：
  名称：

  Stereoselectivity of formation of polycyclic ferrocenyl-4,5-dihydropyrazoles based on E- and Z-s-cis-α,β-enones

  摘要：

  Reaction of E- and Z-isomeric 2-ferrocenylmethylidene-1-tetralone, 2-ferrocenylmethylidene-3-quinuclidinone 1-methyl-3-ferrocenylmethylidene-4-piperidone and 2-ferrocenylmethylidenetropinone with hydrazine proceeds stereospecifically with the-formation of the same diastereomeric polycyclic ferrocenyldihydropyrazoles independently of the geometric configuration of the starting alpha,beta -unsaturated ketones. X-ray structural analysis is presented for the trans-diastereomer of 4-acetyl-3-ferrocenyl-1,4,5-triazatricyclo[5.2.2.0(2,6)]undec-5-ene. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)00761-6