N,N'-propylenebis(ferrocenylmethylidene)imine | 194152-73-3

• 英文名称: N,N'-propylenebis(ferrocenylmethylidene)imine
• CAS: 194152-73-3
• 化学式: C₂₅H₂₆Fe₂N₂
• 分子量: 466.189
• InChiKey: XHWMWDJATKRBGP-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  chloro(1,5-cyclooctadiene)rhodium(I) dimer 、 N,N'-propylenebis(ferrocenylmethylidene)imine 、 silver perchlorate 以 丙酮 、 甲苯 为溶剂， 以84%的产率得到[Rh(1,5-cyclooctadiene)(N,N'-propylenebis(ferrocenylmethylidene)imine)]ClO4
  参考文献：
  名称：

  Solvent-free synthesis of bisferrocenylimines and their rhodium(I) complexes

  摘要：

  The solvent-free reaction of ferrocenecarboxaldehyde and diaminoalkanes under solvent-free conditions gave bisferrocenylimines (L) in excellent yields Cationic rhodium(I) complexes with the formulation [Rh(COD))(L)]ClO4 were prepared by the reaction of [Rh(COD)Cl](2). with the bisferrocenylimines in the presence of silver perchlorate The compounds were characterised by NMR, IR, MS and elemental analysis The X-ray crystal structures of two rhodium(I) complexes are also reported (C) 2009 Elsevier Ltd. All rights reserved

  DOI：

  10.1016/j.poly.2009.11.017
• 作为产物：
  描述：

  二茂铁甲醛 、 1,3-丙二胺 以 neat (no solvent, solid phase) 为溶剂， 以94%的产率得到N,N'-propylenebis(ferrocenylmethylidene)imine
  参考文献：
  名称：

  Solvent-free synthesis of bisferrocenylimines and their rhodium(I) complexes

  摘要：

  The solvent-free reaction of ferrocenecarboxaldehyde and diaminoalkanes under solvent-free conditions gave bisferrocenylimines (L) in excellent yields Cationic rhodium(I) complexes with the formulation [Rh(COD))(L)]ClO4 were prepared by the reaction of [Rh(COD)Cl](2). with the bisferrocenylimines in the presence of silver perchlorate The compounds were characterised by NMR, IR, MS and elemental analysis The X-ray crystal structures of two rhodium(I) complexes are also reported (C) 2009 Elsevier Ltd. All rights reserved

  DOI：

  10.1016/j.poly.2009.11.017