5,5-diacetoxy-1,3,7,9-tetramethyl-5H-5l4-dipyrrolo[1,2-c:2',1'-f][1,3,2]diazaborinin-4-ium | 1352285-60-9

• 英文名称: 5,5-diacetoxy-1,3,7,9-tetramethyl-5H-5l4-dipyrrolo[1,2-c:2',1'-f][1,3,2]diazaborinin-4-ium
• CAS: 1352285-60-9
• 化学式: C₁₇H₂₁BN₂O₄
• 分子量: 328.176
• InChiKey: DUFQKBZBTVHPHB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  三甲基硅乙酸酯 、 4,4-二氟-1,3,5,7-四甲基-4-硼杂-3a,4a-二氮杂对称引达省 以 1,2-二氯乙烷 为溶剂， 反应 40.0h， 以52.1 mg的产率得到5-acetoxy-5-fluoro-1,3,7,9-tetramethyl-5H-5l4-dipyrrolo[1,2-c:2',1'-f][1,3,2]diazaborinin-4-ium
  参考文献：
  名称：

  Development of Mono- and Di-AcO Substituted BODIPYs on the Boron Center

  摘要：

  Mono- and di-AcO substituted BODIPYs (1 and 2) were synthesized from TM-BDP. The structures of 1 and 2 were supported by single crystal X-ray analysis. Both 1 and 2 possess a large absorption coefficient, high fluorescence quantum yield, and high light stability. Compound 2 has much Improved water solubility which is highly desirable for biological applications. Theoretical calculation supports our observations In X-ray analysis, absorption, and cyclic voltammetry.

  DOI：

  10.1021/ol2030229