[Co(bis-pyrazolylpyridine)Cl2]2·CoCl2 | 1575816-18-0

• 英文名称: [Co(bis-pyrazolylpyridine)Cl2]2·CoCl2
• CAS: 1575816-18-0
• 化学式: C₃₈H₅₀Cl₆Co₃N₁₀
• 分子量: 1036.58
• InChiKey: QZTPGFNAUHBQOZ-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,6-二（1-吡唑基）吡啶 、 cobalt(II) chloride 以 四氢呋喃 为溶剂， 反应 2.0h， 以100%的产率得到[Co(bis-pyrazolylpyridine)Cl2]2·CoCl2
  参考文献：
  名称：

  Transition Metal Chlorides Are Lewis Acids toward Terminal Chloride Attached to Late Transition Metals

  摘要：

  Two different neutral tridentate imine-donor pincer ligands interact with excess MCl2 (M = Co or Cu) to form compounds of the same stoichiometry, (LMCl2)(2)center dot MCl2, where the assembling force is the electron richness of the terminal chlorides on the LMCl2 unit. Finite aggregation occurs for M = Co, but for M = Cu, an infinite polymeric structure is adopted, all because MCl2 is bifunctional, which thus bridges multiple MCl units. The bis-pyrazolylpyridine ligand has two acidic NH protons, and both of these are involved in intramolecular hydrogen bonds. The generality of this Lewis acid aggregation is discussed.

  DOI：

  10.1021/ic402107z