fac-[Re(CO)3(bis(2-(1-methylimidazolyl)methyl)amine]Br | 1008757-16-1

• 英文名称: fac-[Re(CO)3(bis(2-(1-methylimidazolyl)methyl)amine]Br
• CAS: 1008757-16-1
• 化学式: Br*C₁₃H₁₅N₅O₃Re
• 分子量: 555.405
• InChiKey: FJRRGJNCCYVBCA-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (NEt4)2[rhenium(I)(bromide)3(carbonyl)3] 、 bis<(1-methylimidazol-2-yl)methyl>amine 以 甲醇 为溶剂， 以88%的产率得到fac-[Re(CO)3(bis(2-(1-methylimidazolyl)methyl)amine]Br
  参考文献：
  名称：

  Imidazole-based bifunctional chelates for the “fac-[Re(CO)3]+” core

  摘要：

  Three monocationic rhenium(I) complexes of the type [Re(CO)(3)(L)]Br, containing the bis-imidazole tridentate ligands bis-(2-(1-methylimidazolyl)methyl)amine (L), bis-(2-(I-methylimidazolyl)methyl)aminoethanoI (L 2) and bis-(2-(benzimidazolyl)ethyl)sulfide (L-3), were prepared and characterized by H-1 NMR and IR spectroscopy. The complex. salt [Re(CO)(3)(L-2)]Br (2) was also characterized by X-ray crystallography. The structure consists of discrete monocationic monomers with a fac-[Re(CO)(3)](+) coordination unit, and the remaining three sites are occupied by one amine and two imidazolyl nitrogen donor atoms. (C) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2007.09.022