([(2,6-bis[(4-phenyl-1H-1,2,3-triazol-1-yl)methyl]pyridine)Ag](SbF6)).infin. | 1211094-90-4

• 英文名称: ([(2,6-bis[(4-phenyl-1H-1,2,3-triazol-1-yl)methyl]pyridine)Ag](SbF6)).infin.
• CAS: 1211094-90-4
• 化学式: Ag*C₂₃H₁₉N₇*F₆Sb
• 分子量: 737.059
• InChiKey: KFTDGCFMVRXMHA-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  silver hexafluoroantimonate 、 2,6-bis(4-phenyl-1,2,3-triazol-1-yl-methyl)pyridine 以 二氯甲烷 、 丙酮 为溶剂， 以86%的产率得到([(2,6-bis[(4-phenyl-1H-1,2,3-triazol-1-yl)methyl]pyridine)Ag](SbF6)).infin.
  参考文献：
  名称：

  A one pot multi-component CuAAC “click” approach to bidentate and tridentate pyridyl-1,2,3-triazole ligands: Synthesis, X-ray structures and copper(II) and silver(I) complexes

  摘要：

  A one pot, multi-component CuAAC reaction has been developed for the generation of alkyl, benzyl or aryl substituted bi and tridentate pyridyl-1,2,3-triazole ligands from their corresponding halides, sodium azide and alkynes in excellent yields. The ligands have been fully characterized by elemental analysis, HR-ESMS, IR, H-1 and C-13 NMR and in the ferrocenyl substituted cases the structures were confirmed by X-ray crystallography. Additionally, we have examined the coordination chemistry of these ligands and found that a variety of geometrically diverse Cu(II) and Ag(I) complexes, including interesting tri and tetrasilver complexes, can be formed. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.06.010