(1-Me-Ind)Ni(PCy3)(CC-Ph) | 255736-80-2

• 英文名称: (1-Me-Ind)Ni(PCy3)(CC-Ph)
• CAS: 255736-80-2
• 化学式: C₃₆H₄₇NiP
• 分子量: 569.433
• InChiKey: AMXHIGLBPISBRA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (1-Me-Ind)Ni(PPh3)(CC-Ph) 、 三环己基膦 以 四氢呋喃 为溶剂， 以68%的产率得到(1-Me-Ind)Ni(PCy3)(CC-Ph)
  参考文献：
  名称：

  Preparation and Characterization of (1-Me-indenyl)Ni(PR₃)(CC−Ph) (R = Cy, Ph) and Alkyne Polymerization Catalysis

  摘要：

  The complexes (1-Me-Ind)(PR3)Ni-CC-Ph (R = Ph and Cy) have been prepared and characterized spectroscopically and by means of single-crystal structural analyses. These compounds are inert toward the insertion of alkynes, but when combined with methylaluminoxane (MAO), they form active catalysts for the homogeneous polymerization of phenylacetylene. cis-Poly(Ph-CC-H) is thus obtained with M-w values in the range of 10(4) and relatively narrow polydispersities. The combination of the corresponding Ni-Cl complexes with MAO gives similar results with Ph-CC-H and also polymerizes 1-hexyne and 3-hexyne, but the degree of polymerization is much lower. Optimization studies have shown that the polymerization reactions give the best results with THF as solvent and a 1:10 ratio of Ni to MAO. Evidence is presented for the involvement in the catalytic cycle of bimetallic species with a Ni(mu-X)(mu-Me)Al core.

  DOI：

  10.1021/om990600a