bis(η(5)-9-fluorenyl)-1-hexylmethylsilane zirconium dichloride | 182349-07-1

• 英文名称: bis(η(5)-9-fluorenyl)-1-hexylmethylsilane zirconium dichloride
• CAS: 182349-07-1
• 化学式: C₃₃H₃₂Cl₂SiZr
• 分子量: 618.833
• InChiKey: NMCFEINJWUOCKN-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  bis(9-fluorenyl)-1-hexylmethylsilane 、 氯化锆(IV) 在 正丁基锂 作用下， 以 乙醚 为溶剂， 以47%的产率得到bis(η(5)-9-fluorenyl)-1-hexylmethylsilane zirconium dichloride
  参考文献：
  名称：

  Polymerization of ethylene with metallocene/methylaluminoxane catalysts supported on polysiloxane micro gels and silica

  摘要：

  Two kinds of fluorenyl containing zirconocene catalysts, supported on polymethyisiloxane micro gels and on silica, were prepared and applied for ethylene polymerizations using methylaluminoxane as cocatalyst. The observed activities were comparable with those of the corresponding silica supported catalysts. The average molecular weights of the obtained polymers differ from those of the corresponding homogeneous catalysts as from those of the silica supported systems. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)00841-9