(ferrocenylmethyl)(3-hydroxy-2-methylprop-2-yl)ammonium dihydrogenphosphate | 680622-42-8

• 英文名称: (ferrocenylmethyl)(3-hydroxy-2-methylprop-2-yl)ammonium dihydrogenphosphate
• CAS: 680622-42-8
• 化学式: C₁₅H₂₁FeNO*H₃O₄P
• 分子量: 385.18
• InChiKey: FQDFKQGZDXSXFS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2-(ferrocenylmethyl)amino-2-methyl-propan-1-ol 、 磷酸 以 甲醇 、 水 为溶剂， 以99%的产率得到(ferrocenylmethyl)(3-hydroxy-2-methylprop-2-yl)ammonium dihydrogenphosphate
  参考文献：
  名称：

  Acid-base and counter ion dependent solid-state assembly of a ferrocene β-aminoalcohol and the corresponding ammonium salt

  摘要：

  2-(Ferrocenylmethyl)amino-2-methylpropan-1-ol was synthesized and converted to the respective ammonium bromide ([1H]Brdrop2) and dihydrogenphosphate ([1H]H(2)PO(4)drop3). The solid-state structures of 1, 2 and the solvated salt 3(.)1/6Et(2)O (3a) have been determined by X-ray diffraction. The solid-state assemblies of 1 and 2 are dominated by infinite ladder-like arrays interconnected by hydrogen bonds whereas the solid-state structure of 3a is built up from linear hydrogen-bonded dihydrogenphosphate chains, which are interlinked via hydrogen bonds to the cations [1H](+) into a complicated three-dimensional network. Compound 1 and its interactions with Bu4NBr and Bu4NH2PO4 in solution were further studied by electrochemical methods and NMR titrations. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2003.11.017