phenyllead triacetate * H2O | 37971-10-1

• 英文名称: phenyllead triacetate * H2O
• CAS: 37971-10-1
• 化学式: C₁₂H₁₄O₆Pb*H₂O
• 分子量: 479.455
• InChiKey: FAFVZVMOVVJAEM-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  二苯基汞 、 lead(IV) acetate 以 甲苯 为溶剂， 以49%的产率得到phenyllead triacetate * H2O
  参考文献：
  名称：

  Untersuchungen an Arylbleitriacetaten. Röntgenstrukturanalyse von 2-methylphenyl-und 2-chlorphenylbleitriacetat

  摘要：

  The crystal structures of 2-XC6H4Pb(OAc)3 (X = CH3, Cl; OAc = OOCCH3) have been determined by X-ray diffraction. Both compounds are isostructural and crystallize as triclinic, space group P1BAR. They consist of monomers, the seven-coordinated central atom being in a distorted pentagonal-bipyramidal environment with five O atoms of the three unsymmetrically chelating carboxylate groups in equatorial positions, and one O and one C(aryl) atom in axial positions. IR, H-1, C-13 and Pb-207 NMR spectroscopic data of these and other monoaryllead triacetates are reported, and similar structures with seven-coordinated lead are inferred. Weak coordination of Y to Pb is discussed to exist possibly in 2-YC6H4Pb(OAc)3(Y = F, Cl, OCH3).

  DOI：

  10.1016/0022-328x(92)83382-r