[Co(1,3-bis(2-pyridylmethylthio)propane)Cl2] | 1161444-52-5

• 英文名称: [Co(1,3-bis(2-pyridylmethylthio)propane)Cl2]
• CAS: 1161444-52-5；221295-96-1
• 化学式: C₁₅H₁₈Cl₂CoN₂S₂
• 分子量: 420.353
• InChiKey: XOOFJLXNRNAAGW-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  cobalt(II) chloride hexahydrate 、 1,3-bis(2-pyridylmethylthio)propane 以 甲醇 为溶剂， 以71%的产率得到[Co(1,3-bis(2-pyridylmethylthio)propane)Cl2]
  参考文献：
  名称：

  Synthesis and crystal structure characterization of iron(II), cobalt(II) and nickel(II) complexes with 1,3-bis(2-pyridylmethylthio)propane

  摘要：

  Three new mononuclear complexes of nitrogen-sulfur donor sets, formulated as (Fe-II(L)Cl-2] (1), [Co-II(L)Cl-2] (2) and [Ni-II(L)Cl-2] (3) where L = 1,3-bis(2-pyridylmethylthio)propane, were synthesized and isolated in their pure form. All the complexes were characterized by physicochemical and spectroscopic methods. The solid state structures of complexes I and 3 have been established by single crystal X-ray crystallography. The structural analysis evidences isomorphous crystals with the metal ion in a distorted octahedral geometry that comprises NSSN ligand donors with trans located pyridine rings and chlorides in cis positions. In dimethylformamide solution, the complexes were found to exhibit Fe-II/Fe-III, co(II)/co(III) and Ni-II/Ni-III quasi-reversible redox couples in cyclic voltammograms with E-1/2 values (versus Ag/AgCl at 298 K) of +0.295, +0.795 and +0.745 V for 1, 2 and 3, respectively. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.02.039