[(ferrocenylmethylpyrazole)AuP(C6H5)3][CF3SO3] | 873932-90-2

• 英文名称: [(ferrocenylmethylpyrazole)AuP(C6H5)3][CF3SO3]
• CAS: 873932-90-2
• 化学式: CF₃O₃S*C₃₂H₂₉AuFeN₂P
• 分子量: 874.453
• InChiKey: KYLFYKMDBHMQDH-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  trifluoromethanesulfonyloxy(triphenylphosphine)gold(I) 、 1-ferrocenylmethyl-1H-pyrazole 以 二氯甲烷 为溶剂， 以65%的产率得到[(ferrocenylmethylpyrazole)AuP(C6H5)3][CF3SO3]
  参考文献：
  名称：

  Gold and silver complexes with the ferrocenyl-pyrazolate ligand FcCH2pz

  摘要：

  We have synthesized a series of gold(l), gold(111) or silver(l) derivatives with ferrocenylmethylpyrazole (pzCH(2)Fc) as ligand. X-ray structure determination for [Au(C6F5)(pzCH(2)Fc)] reveals a linear geometry for the gold centre and association of the molecules in pairs through intermolecular gold(I)-gold(I) interactions of 3.1204(6) angstrom. These molecules are further assembled into chains and the chains into a 3D structure through several hydrogen bonds. [Ag(OTf)(pzCH(2)Fc)] (OTf = triflate) is a dimer with a distorted tetrahedral geometry at the silver(l) centre and the triflate acting as bridging ligand. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.02.017