Cp*FeB4H11 | 444843-04-3

• 英文名称: Cp*FeB4H11
• CAS: 444843-04-3
• 化学式: C₁₀H₂₆B₄Fe
• 分子量: 245.407
• InChiKey: XVURSSNTTZMLPU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  dicobalt octacarbonyl 、 Cp*FeB4H11 以 not given 为溶剂， 生成 1,2-(Cp*Fe)(Co(CO)3)B4H8
  参考文献：
  名称：

  Routes to Compounds Containing M−B Bonds. Reaction of [Cp*FeH₂]₂ with BH₃·THF, Yielding the Hydrogen-Rich arachno-Ferrapentaborane 1-Cp*FeB₄H₁₁ (Cp* = η⁵-C₅Me₅)

  摘要：

  The reaction of [Cp*FeH2](2) (Cp* = eta(5)-C5Me5) with BH3.THF under mild conditions produces the new arachno-ferraborane 1-Cp*FeB4H11 via a boraallyl intermediate. Reaction of 1-Cp*FeB4H11 with CO2(CO)(8) yields the novel nido-dimetallahexaborane 1,2-(Cp*Fe)-{Co(CO)(3)}B4H8, which has been characterized by an X-ray diffraction structure determination.

  DOI：

  10.1021/om020273y
• 作为产物：
  描述：

  硼烷四氢呋喃络合物 、 [((η5-C5Me5)Fe)2(μ-H)4] 以 not given 为溶剂， 生成 Cp*FeB4H11
  参考文献：
  名称：

  Routes to Compounds Containing M−B Bonds. Reaction of [Cp*FeH₂]₂ with BH₃·THF, Yielding the Hydrogen-Rich arachno-Ferrapentaborane 1-Cp*FeB₄H₁₁ (Cp* = η⁵-C₅Me₅)

  摘要：

  The reaction of [Cp*FeH2](2) (Cp* = eta(5)-C5Me5) with BH3.THF under mild conditions produces the new arachno-ferraborane 1-Cp*FeB4H11 via a boraallyl intermediate. Reaction of 1-Cp*FeB4H11 with CO2(CO)(8) yields the novel nido-dimetallahexaborane 1,2-(Cp*Fe)-{Co(CO)(3)}B4H8, which has been characterized by an X-ray diffraction structure determination.

  DOI：

  10.1021/om020273y