{Pd(C2H4)(1,3-bis(diphenylphosphino)propane)} | 149478-10-4

• 英文名称: {Pd(C2H4)(1,3-bis(diphenylphosphino)propane)}
• CAS: 149478-10-4
• 化学式: C₂₉H₃₀P₂Pd
• 分子量: 546.925
• InChiKey: CWQOQYXFBOXKCT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  {Pd(C2H4)(1,3-bis(diphenylphosphino)propane)} 、 1,2-双(二环己基磷基)-乙烷 以 四氢呋喃 为溶剂， 生成 [Pd(dppp)₂] 、 {Pd(1,2-bis(dicyclohexylphosphino)ethane)2}
  参考文献：
  名称：

  Mixed biphosphine complexes of palladium(0); the structure of “bis(diphenylphosphino)ethane”-“bis(dicyclohexylphosphino)ethane” palladium(0)

  摘要：

  A range of mixed biphosphine complexes of palladium(0) has been prepared and characterized by P-31 NMR spectroscopy. The complexes disproportionate in solution at rates which depend on the nature of the ligands. The structure of [Pd(dcpe)(dppe)] has been established in an X-ray diffraction study.

  DOI：

  10.1016/s0277-5387(00)81751-9
• 作为产物：
  描述：

  {Pd(1,2-bis(diphenylphosphanyl)ethane)(C2H4)} 、 1,3-双(二苯基膦)丙烷 以 四氢呋喃 为溶剂， 生成 双(1,2-双(二苯基膦)乙烷)钯 、 [Pd(dppp)₂] 、 {Pd(C2H4)(1,3-bis(diphenylphosphino)propane)}
  参考文献：
  名称：

  Mixed biphosphine complexes of palladium(0); the structure of “bis(diphenylphosphino)ethane”-“bis(dicyclohexylphosphino)ethane” palladium(0)

  摘要：

  A range of mixed biphosphine complexes of palladium(0) has been prepared and characterized by P-31 NMR spectroscopy. The complexes disproportionate in solution at rates which depend on the nature of the ligands. The structure of [Pd(dcpe)(dppe)] has been established in an X-ray diffraction study.

  DOI：

  10.1016/s0277-5387(00)81751-9