Re(NPh)(OEt)Cl2(dppf) | 352467-62-0

• 英文名称: Re(NPh)(OEt)Cl2(dppf)
• CAS: 352467-62-0
• 化学式: C₄₂H₃₈Cl₂FeNOP₂Re
• 分子量: 947.677
• InChiKey: LZRGWOHESNYCFN-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  fac-Re(NPh)Cl3(dppf) 、 乙醇锂 以 乙醇 为溶剂， 生成 Re(NPh)(OEt)Cl2(dppf)
  参考文献：
  名称：

  Re(V)–oxo–dppf and Re(V)–imido–dppf complexes: synthesis, structure, and properties of Re(X)Cl3(dppf) (X=O, NPh, N-C6H3-2,6-i-Pr2; dppf=Fe(η5-C5H4PPh2)2)

  摘要：

  Re(V)-imido and Re(V)-oxo complexes containing 1,1 ' -bis(diphenylphosphino)ferrocene (Fe(eta (5)-C5H4PPh2)(2), dppf) were prepared from mer,trans-Re(O)Cl-3(PPh3)(2) (1), mer,trans-Re(NPh)Cl-3(PPh3)(2) (2), or mer,cis-Re(N-C6H3-2,6-i-Pr-2)(2)Cl-3(py) (3). Compounds 1-3 reacted with dppf to give fac-Re(O)Cl-3(dppf) (4), fac-Re(NPh)Cl-3( dppf) (5), and mer-Re(N-C6H3-2,6-i-Pr-2)Cl-3(dppf) (6), respectively. Electrochemical studies performed on Re-oxo-dppf complexes (4) and Re- imido-dppf complexes (5 and 6) showed different redox behavior depending on the type of ligand coordinated to the Re metal. The structure of compound 4 was determined by X-ray diffraction. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)00754-9