[Cp2Ce(η3-N(SPPh2)2)] | 899827-89-5

• 英文名称: [Cp2Ce(η3-N(SPPh2)2)]
• CAS: 899827-89-5
• 化学式: C₃₄H₃₀CeNP₂S₂
• 分子量: 718.818
• InChiKey: KXJXUGXBOVLIBL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  三(氰基式二烯基)铈 、 bis(diphenylthiophosphinoyl)amine 以 四氢呋喃 为溶剂， 生成 Cp₃Ce(THF) 、 [Cp2Ce(η3-N(SPPh2)2)]
  参考文献：
  名称：

  Syntheses and characterization of Cp2Ce[η3-N(QPPh2)2] (Q=S, Se) and Cp2Ce[η3-N(SPiPr2)(SePPh2)]

  摘要：

  The compounds Cp2Ce[eta(3)-N(QPPh(2))(2)] (Q = S (1), Se (2)) and Cp2Ce[eta(3)-N((SPPr2)-Pr-i)(SePPh2)] (3) have been synthesized from the protonolysis reactions between Cp3Ce and HN(QPPh(2))(2) or HN((SPPr2)-Pr-i)(SePPh2) in THK The structures of these compounds have been determined by X-ray crystallographic methods. The three compounds have similar structures in which the ligands are coordinated to Cp2Ce moiety in an eta(3) fashion through the two chalcogen atoms and an N atom. Whereas the Se-77 NMR resonances are normal the P-31 NMR resonances are shifted to much lower frequencies than in similar rare-earth compounds. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.10.029