Gallium--ruthenium (2/1) | 12064-21-0

• 英文名称: Gallium--ruthenium (2/1)
• 英文别名: gallane;ruthenium
• CAS: 12064-21-0
• 化学式: Ga₂Ru
• 分子量: 240.516
• InChiKey: QATFLFQAFJDSLX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -2.37
• 重原子数：
  3
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  (η4-cyclooctadiene)Ru(Ga(η5-C5(CH3)5))3 在 H₂ 作用下， 以 均三甲苯 为溶剂， 生成 、 Gallium--ruthenium (2/1)
  参考文献：
  名称：

  Cadenbach, Thomas; Gemel, Christian; Schmid, Rochus, Angewandte Chemie - International Edition, 2009, vol. 48, p. 3872 - 3876

  摘要：

  DOI：

文献信息

• Evers, Juergen; Oehlinger, Gilbert; Meyer, Heinrich, Materials Research Bulletin, 1984, vol. 19, p. 1177 - 1180
  作者：Evers, Juergen、Oehlinger, Gilbert、Meyer, Heinrich

  DOI：——

  日期：——
• Thermoelectric figure of merit enhancement of intermetallic compound RuGa2 by ball-milling
  作者：N. Sato、Y. Matsuura、K. Kitahara、Y. Takagiwa、K. Kimura

  DOI：10.1016/j.jallcom.2013.09.175

  日期：2014.2

  The effect of introducing a fine grain boundary using ball-milling to increase phonon scattering on the thermoelectric figure of merit of the binary semiconducting intermetallic compound RuGa2 has been investigated. The studied samples were synthesized by a combination of arc-melting, ball-milling, and spark plasma sintering (SPS). The average grain size of the bulk sample sintered by SPS from milled powder was 10-20 times larger than that of the original nanopowders, which ranged from 5 to 30 nm in size. The total thermal conductivity of the RuGa2, which had a grain size of more than 1 mu m, decreased by 31% at room temperature after milling. The maximum dimensionless figure of merit, ZT(max), of milled RuGa2 was 0.58 at 773 K, a 7% and 16% enhancement on the value of 0.54 for unmilled RuGa2 and the highest reported value of 0.50, respectively. Further enhancement in ZT can be expected by preserving the size of the milled nanopowders. (C) 2013 Elsevier B. V. All rights reserved.