| 1377950-54-3

• CAS: 1377950-54-3
• 化学式: C₆₁H₈₅N₂O₄SiU
• 分子量: 1176.47
• InChiKey: UZAPTAOGNCZDLM-AQBGSFDMSA-K

反应信息

• 作为产物：
  描述：

  叠氮基三甲基硅烷 、 [(tris(2-hydroxy-3-adamantyl-5-medimethylthylbenzyl)amine)U(DME)] 以 乙醚 为溶剂， 以80%的产率得到
  参考文献：
  名称：

  Observation of the Inverse Trans Influence (ITI) in a Uranium(V) Imide Coordination Complex: An Experimental Study and Theoretical Evaluation

  摘要：

  An inverse trans influence has been observed in a high-valent U(V) imide complex, [(((ArO)-Ar-Ad)(3)N)U(NMes)]. A thorough theoretical evaluation has been employed in order to corroborate the ITI in this unusual complex. Computations on the target complex, [(((ArO)-Ar-Ad)(3)N)U(NMes)], and the model complexes [(((ArO)-Ar-Me)(3)N)U(NMes)] and [(NMe3)(OMe2)(OMe)(3)U(NPh)] are discussed along with synthetic details and supporting spectroscopic data. Additionally, the syntheses and full characterization data of the related U(V) trimethylsilylimide complex [(((ArO)-Ar-Ad)(3)N)U(NTMS)] and U(IV) azide complex [(((ArO)-Ar-Ad)(3)N)U(N-3)] are also presented for comparison.

  DOI：

  10.1021/ic300273d