Vinyltriethylsilane(hexafluoroacetylacetonate)silver(I) | 177279-28-6

• 英文名称: Vinyltriethylsilane(hexafluoroacetylacetonate)silver(I)
• 英文别名: (1,1,1,5,5,5-hexafluoro-2,4-pentanedionato)Ag(vinyltriethylsilane)
• CAS: 177279-28-6
• 化学式: C₁₃H₁₉AgF₆O₂Si
• 分子量: 457.237
• InChiKey: NOZBMIUMPBIWNS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

安全信息

• 安全说明：
  S26,S36/37/39
• 危险类别码：
  R36/37/38

反应信息

• 作为产物：
  描述：

  三乙基乙烯基硅烷 、 六氟乙酰丙酮 、 silver(l) oxide 以 乙醚 为溶剂， 以82%的产率得到Vinyltriethylsilane(hexafluoroacetylacetonate)silver(I)
  参考文献：
  名称：

  Synthesis and Characterization of (β-Diketonato)silver Vinyltriethylsilane Compounds and Their Application to CVD of Silver Thin Films. Crystal Structure of the (2,2-Dimethyl-6,6,7,7,8,8,8-heptafluoro-3,5-octanedionato)silver Vinyltriethylsilane Dimer

  摘要：

  New silver complexes of alkenes of empirical formula (beta-diketonato)Ag(VTES), where beta-diketonato = 1,1,1,5,5,5-hexafluoro-2,4-pentanedionato (hfac), (1),1,1,1-trifluoro-2,4-pentanedionato (hfac) (2), and 2,2-dimethyl-6,6,7,7,8,8,8-heptafluoro-3,5-octanedionato (fod) (3) and VTES = vinyltriethylsilane, were prepared from reactions of Ag2O with beta-diketones in the presence of VTES. All compounds were characterized by elemental analyses and H-1, C-13, and F-19 NMR and IR spectra. The crystal structure of compound 3 determined by X-ray diffraction analysis showed a dimeric silver species with coordination of the C=C double bond of VTES, two oxygen atoms of a chelating fod ligand, and the methine C atom of another fod in the solid state. Hot-wall chemical vapor deposition experiments revealed that compound 1 is suitable as a precursor to deposit pure silver films in the temperature range 160-280 degrees C.

  DOI：

  10.1021/om960013e