fac-W(CO)3(η(2)-1,1'-bis(diphenylphosphino)ferrocene)(PPh2H) | 163162-58-1

• 英文名称: fac-W(CO)3(η(2)-1,1'-bis(diphenylphosphino)ferrocene)(PPh2H)
• CAS: 163162-58-1
• 化学式: C₄₉H₃₉FeO₃P₃W
• 分子量: 1008.47
• InChiKey: AWCUXEXNGQVOLA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  fac-W(CO)3(acetonitrile)(η(2)-1,1'-bis(diphenylphosphino)ferrocene) 、 二苯基氯化膦 以 二氯甲烷 为溶剂， 以34%的产率得到fac-W(CO)3(η(2)-1,1'-bis(diphenylphosphino)ferrocene)(PPh2H)
  参考文献：
  名称：

  Syntheses and characterization of tricarbonyl tungsten complexes containing 1,1′-bis(diphenylphosphino) ferrocene ligand

  摘要：

  Treatment of W(CO)(3)(NCCH3)(3) with 1,1'-bis(diphenylphosphino)ferrocene (dppf) affords W(CO)(3)(NCCH3)(eta(2)-dppf) (1) in 85%) yield. Reaction of 1 with I-2 produces a seven-coordinated complex W(CO)(2)(I)(2)(eta(2)-dppf) (2), which is further oxidized by H2O2 to give W(CO)(3)(I)(2)(eta(2)-dppf(=O)) (3) in 80% yield. Compound 1 reacts with PMe(3) forming fac-W(CO)(3)(eta(2)-dppf)(PMe(3)) (4) in 90% yield. However, reaction of 1 with PPh(2)Cl generates fac-W(CO)(3)(eta(2)-dppf)(PPh(2)H) (5) and fac-W(CO)(3)(eta(2)-dppf)(PPh(2)OH) (6) after separation of the reaction mixture by TLC. The structures of compounds 1 and 3 have been characterized by X-ray diffraction methods.

  DOI：

  10.1016/0022-328x(95)05413-j