[κ(3)-((hydrotris(3,5-bis(isopropyl)pyrazolyl)borate)]Ru(κ(2)-2,2'-bipyridine)(κ(1)-OH)(CF3SO3) | 677710-78-0

• 英文名称: [κ(3)-((hydrotris(3,5-bis(isopropyl)pyrazolyl)borate)]Ru(κ(2)-2,2'-bipyridine)(κ(1)-OH)(CF3SO3)
• CAS: 677710-78-0
• 化学式: CF₃O₃S*C₃₇H₅₅BN₈ORu
• 分子量: 888.848
• InChiKey: OOAAAHSLGFHQJB-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  四氢呋喃 、 [κ(3)-((hydrotris(3,5-bis(isopropyl)pyrazolyl)borate)]Ru(κ(2)-2,2'-bipyridine)(κ(1)-OH)(CF3SO3) 以 四氢呋喃 、 正己烷 为溶剂， 生成 [κ(3)-((hydrotris(3,5-bis(isopropyl)pyrazolyl)borate)]Ru(pyridine)(H2O)2(OH)(THF)2(CF3SO3)*THF
  参考文献：
  名称：

  Oxygenation of a series of cationic aquoruthenium complexes, TpiPr2Ru(OH2) L3–· CF3SO3· (THF) , leading to mono- and dinuclear aquo-hydroxo complexes supported by unique hydrogen bonding networks

  摘要：

  O-2-treatment of the labile cationic aquo-Ru(II) complexes, Tp(iPr2)(L)(n)Ru(OH2)(3-n)(OTf)(THF)(x) [L = bipy (1d), py (2), THF (3)], results in oxidation of the metal center to give the mononuclear hydroxo-Ru(III) complexes, [Tp(iPr2) (bipy)Ru-III (OH)](OTf) (4), Tp(iPr2) (py)Ru-III (OH)(OH2)(OTf)(THF)(2) (5), and the dinuclear Ru(II)-Ru(III) and Ru(III)-Ru(III) mixed aquo-hydroxo complexes bridged by the Ru-O...H...O-Ru hydrogen-bonding interactions, Tp(iPr2) Ru-II(OH)(2)(OH2)(4)(OTf)Ru(III)Tp(iPr2) (6) and (Tp(ipr2)Ru)(2)(OH)(2)(OH2)(4)(OTf)(2) (7). (C) 2003 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2003.11.009
• 作为产物：
  描述：

  [(hydrotris(3,5-bis(isopropyl)pyrazolyl)borate]Ru(2,2'-bipyridine)(OH)2(CF3SO3) 在 O₂ 作用下， 以 四氢呋喃 为溶剂， 以78%的产率得到[κ(3)-((hydrotris(3,5-bis(isopropyl)pyrazolyl)borate)]Ru(κ(2)-2,2'-bipyridine)(κ(1)-OH)(CF3SO3)
  参考文献：
  名称：

  Oxygenation of a series of cationic aquoruthenium complexes, TpiPr2Ru(OH2) L3–· CF3SO3· (THF) , leading to mono- and dinuclear aquo-hydroxo complexes supported by unique hydrogen bonding networks

  摘要：

  O-2-treatment of the labile cationic aquo-Ru(II) complexes, Tp(iPr2)(L)(n)Ru(OH2)(3-n)(OTf)(THF)(x) [L = bipy (1d), py (2), THF (3)], results in oxidation of the metal center to give the mononuclear hydroxo-Ru(III) complexes, [Tp(iPr2) (bipy)Ru-III (OH)](OTf) (4), Tp(iPr2) (py)Ru-III (OH)(OH2)(OTf)(THF)(2) (5), and the dinuclear Ru(II)-Ru(III) and Ru(III)-Ru(III) mixed aquo-hydroxo complexes bridged by the Ru-O...H...O-Ru hydrogen-bonding interactions, Tp(iPr2) Ru-II(OH)(2)(OH2)(4)(OTf)Ru(III)Tp(iPr2) (6) and (Tp(ipr2)Ru)(2)(OH)(2)(OH2)(4)(OTf)(2) (7). (C) 2003 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2003.11.009