| 148574-82-7

• CAS: 148574-82-7
• 化学式: C₇H₆BrIMoN₂O₃
• 分子量: 468.885
• InChiKey: YJRAVZLHWZLTOJ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  在 二氯甲烷 、 三苯基膦 作用下， 以 二氯甲烷 为溶剂， 以64%的产率得到
  参考文献：
  名称：

  The preparation and reactions with donor ligands of [MoBrI(CO)3(NCMe)2]

  摘要：

  Equimolar quantities of fac-[Mo(CO)3(NCMe)3] {prepared in situ by reacting [Mo(CO)6] in refluxing acetonitrile for 24 h} and BrI react at 0-degrees-C to give the seven-coordinate complex [MoBrI(CO)3(NCMC)2] (1). Complex 1 reacts with 1 equivalent of L (L = PPh3, ASPh3 or SbPh3) to initially give the mono(acetonitrile) complexes [MoBrI(CO)3(NCMe)L], which subsequently dimerize to afford [Mo(mu-I)Br(CO)3L]2. Reaction of 1 with 2 equivalents of L (L = PPh3, AsPh3 Or SbPh3) gives the bis(ligand) compounds [MoBrl(CO)3L2]. The preparation and characterization of a series of new mixed-ligand complexes [MoBrl(CO)3LL'] [L = PPh3, L' = AsPh3; L = PPh3, L' = SbPh3; L = AsPh3, L' = SbPh3; L = PPh3, AsPh3 and SbPh3; L' = SPPh3, SC(NH2)2 and SC(NMe2)2] are also described. Equimolar quantities of LL [LL = Ph2P(CH2)nPPh2 (n = 1-3); 1,10-phen] and [MoBrl(CO)3(NCMe)2] react to afford the acetonitrile displaced products [MoBrl(CO)3(LL)] in high yield. The synthesis of the novel, dicarbonyl five different ligand compound [MoBrI(CO)2(NCMe)(SbPh3)2] is also reported.

  DOI：

  10.1016/s0277-5387(00)81738-6
• 作为产物：
  描述：

  一溴化碘 、 乙腈 、 molybdenum hexacarbonyl 以 乙腈 为溶剂， 以92%的产率得到
  参考文献：
  名称：

  The preparation and reactions with donor ligands of [MoBrI(CO)3(NCMe)2]

  摘要：

  Equimolar quantities of fac-[Mo(CO)3(NCMe)3] {prepared in situ by reacting [Mo(CO)6] in refluxing acetonitrile for 24 h} and BrI react at 0-degrees-C to give the seven-coordinate complex [MoBrI(CO)3(NCMC)2] (1). Complex 1 reacts with 1 equivalent of L (L = PPh3, ASPh3 or SbPh3) to initially give the mono(acetonitrile) complexes [MoBrI(CO)3(NCMe)L], which subsequently dimerize to afford [Mo(mu-I)Br(CO)3L]2. Reaction of 1 with 2 equivalents of L (L = PPh3, AsPh3 Or SbPh3) gives the bis(ligand) compounds [MoBrl(CO)3L2]. The preparation and characterization of a series of new mixed-ligand complexes [MoBrl(CO)3LL'] [L = PPh3, L' = AsPh3; L = PPh3, L' = SbPh3; L = AsPh3, L' = SbPh3; L = PPh3, AsPh3 and SbPh3; L' = SPPh3, SC(NH2)2 and SC(NMe2)2] are also described. Equimolar quantities of LL [LL = Ph2P(CH2)nPPh2 (n = 1-3); 1,10-phen] and [MoBrl(CO)3(NCMe)2] react to afford the acetonitrile displaced products [MoBrl(CO)3(LL)] in high yield. The synthesis of the novel, dicarbonyl five different ligand compound [MoBrI(CO)2(NCMe)(SbPh3)2] is also reported.

  DOI：

  10.1016/s0277-5387(00)81738-6

文献信息

• Halocarbonyl alkyne complexes of molybdenum (II) : crystal structures of [MoI2 (CO) (NCMe) (η2-RC2R) 2] (R=Me and Ph) and [MoI2 (CO) (5,6-Me2-1,10-phen) (η2-PhC2Ph) ]
  作者：Nicholas G. Aimeloglou、Paul K. Baker、Margaret M. Meehan、Michael G.B. Drew

  DOI：10.1016/s0277-5387(98)00132-6

  日期：1998.9

  2] with RC2R′ in CH2Cl2 at room temperature gave the bis (alkyne) complexes [MoXX′ (CO) (NCMe) (η2-RC2R′) 2] (X=X′=I, R=R′=Me; X=X′=Br, R=R′=Me, Ph; X′=I, X=Cl, Br, R=R′=Me, Ph) (1→7) in high yield. The molecular structures of [MoI2 (CO) (NCMe) (η2-RC2R) 2] (R=Me, Ph) have been determined by X-ray crystallography. The two structures are very similar, with the two alkyne ligands cis- and parallel to

  [MoXX'（CO）的反应3（NCMe）2 ]与RC 2在CH R' 2氯2在室温下，得到双（炔）络合物[MoXX'（CO）（NCMe）（η 2 -RC 2 - [R '）2 ]（X = X'= I，R = R'= Me; X = X'= Br，R = R'= Me，Ph; X'= I，X = Cl，Br，R = R' = Me，Ph）（1→7）的高收率。的[内政部的分子结构2（CO）（NCMe）（η 2 -RC 2 R）2通过X射线晶体学测定]（R ＝ Me，Ph）。这两个结构非常相似，两个炔配体彼此顺式和平行，并与两个碘配体反式。一氧化碳和乙腈配体占据两个轴向位点。的治疗[内政部2（CO）（NCMe）（η 2 -RC 2 PH）2 ]与L的等摩尔量∩ L 多对于R =苯基，L ∩ L = 5,6--ME 2 -1,10-苯，Ph 2 P（CH 2）2 PPh 2 ; 对于R = Me，L∩L